Study of the structure of graft dextran (dialdehyde dextran)-Polyacrylamide copolymers

Bartoshevich, S.F.; Shishkina, G. V.; Potapenko, V.Ye.; Molotkov, V. A.; Klenin, S.I.

doi:10.1016/0032-3950(89)90302-x

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Synthesis Methods For Branched Polymer Systems1

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2014

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“…The feature of the polymerization initiation by vanadium(V) salts is the necessity of the preliminary introduction of easily oxidized groups into the polymer-base due to a low redox potential [114]. Among the variable valence metal compounds, cobalt(ІІІ) salts are characterized by the highest redox potential, however, in the соpolymerization process they can also initiate the homopolymerization of, e.g., vinyl monomers [115] or lead to a destruction of the main chain of polysaccharides [115][116][117][118].…”

Section: Synthesis Methods For Branched Polymer Systemsmentioning

confidence: 99%

Features of the intramolecular structure of branched polymer systems in solution

2014

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The review is devoted to the synthesis and properties of branched polymer structures of a controlled molecular architecture. The work considers the main methods to obtain branched macromolecules. The results of both theoretical calculations and experimental studies of the structure and features of the behavior of the mentioned systems in solution are analyzed and generalized. The promising use of branched polymer systems as an alternative to linear systems is noted.

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