The effects of air content, mineral admixtures and strength on the freeze-thaw resistance of concrete were studied from the perspective of pore structure. With respect to different size ranges, the pore structures of concrete were analysed at multiple scales and across multiple dimensions by mercury intrusion porosimetry, gas physical adsorption method, linear traverse method and X-ray computerised tomography, respectively. The experimental results indicate that the size and quantitative characteristics of pores which are greater than 0·35 nm in diameter can be obtained by combining these four methods. As simply improving the strength grade tends to decrease the porosity, which further increases the air-void volume and number of harmful pores at a macro-scale, it is not necessarily conducive to improving the frost resistance of concrete. Moreover, when the air content varies from 2% to 6%, the proportion of tiny closed pores in concrete increases significantly, the spacing factor and average diameter decrease in turn, and the frost resistance improves with increasing air content.
IntroductionThe mechanical properties and durability of concrete are affected by the pore structure, including the porosity, pore size, pore size distribution and specific surface area. Wu and Lian (1999) summarised the positive effects of pores and pointed out that the required performance can be obtained by adjusting the structure thereof. Based on Powers' experiment, Neville (2012) indicated that there is no simple functional relationship between the permeability of concrete and porosity, but the permeability mainly depends on the pore structure characteristics. At the seventh international congress of cement chemistry, Wittman (1985) pointed out that the pore structure includes parameters such as porosity, pore size distribution, pore morphology and pore spatial arrangement. Compared with other durability indices, pore structure shows a higher correlation to the damage suffered by concrete under freeze-thaw environments.Research into the durability of concrete under freezingthawing conditions has developed by examining the coupling effects arising from multiple factors combining to operate in a complex environment from a single factor Niu et al., 2013;Tikkanen et al., 2015;Yildirim et al., 2015). The damage resulting from salt has been a research focus in recent years because it is a problem encountered widely. At present, most pore structures are characterised by air content (Li et al., 2015), air-void spacing factor (ASTM, 2006;, porosity, critical pore size (Zhao et al., 2002) and so on. Many researchers have performed experimental investigations of the air-void spacing parameter in hardened concrete. However, the conclusions were quite different and vary from 200 μm to 800 μm. Now mercury intrusion porosimetry (MIP) is used widely, but there is still no satisfactory relationship established between the data and the macro-performance (Zhao et al., 2004).Therefore, in view of the different pore size ranges, MIP, the gas physical a...