Study of the kinetics of the first fast step of solid bismuth ionization by galvanostatic double-pulse method

Theory of square wave voltammetry of three step electrode reaction

“…The theory of this type of reactions is developed for the single and double pulse chronoamperometry [6][7][8], chronopotentiometry [9,10], polarography [11][12][13], cyclic voltammetry [14][15][16] and square wave voltammetry [17]. Electrode reactions of bismuth [18][19][20][21][22][23][24][25][26] and antimony [27] were analyzed. The responses of charge transfers that are kinetically controlled depend on the standard rate constants and transfer coefficients of all slow steps [6,11,12,15,17].…”