Four sample groups were prepared by adding different concentrations of naphthalene (NP) or of 2,6-diisopropylnaphthalene (DIN) as a secondary solvent (S2) in carborane-loaded toluene (TL)-and pseudocumene (PC)-based scintillators. The pulse-height spectra of the samples in response to 137 Cs γ-rays and to thermal neutrons were collected to study the light output (L) enhancement effect of S2. It is found that for all sample groups, L increases to a plateau with the concentration of secondary solvent ([S2]). As [S2] is increased from 0 to saturation concentration, L increases by 31-45% and 34-53% in response to 137 Cs γ-rays and to thermal neurons, respectively. A first-order approximation model is proposed to fit to the experimental data. The enhancement factor (kh) and maximum L of each sample group are obtained from curve fitting. The Birks factor (kB) and electron equivalent energy (keVee) of each sample are calculated by a numerical method based on Birks formula. The L enhancement is discussed according to the percent changes of these parameters. In conclusion, the enhancement effect is attributed mainly to the fused double benzene-ring structure of NP and DIN, which has more delocalized electrons, and provides faster Förster resonance energy transfer paths than the single benzene-ring structure of TL and PC. Adding NP or DIN leads to a significant increase in absolute scintillation efficiency (S) and a slight decrease in kB for both scintillators. It is believed that DIN has slightly larger enhancement effect than NP. A so-called "dynamic quenching" is confirmed to exist in the scintillation process based on the kh values in response to 137 Cs γ-rays and to thermal neutrons.