Please cite this article as: T. Lostak, S. Krebs, A. Maljusch, T. Gothe, M. Giza, M. Kimpel, J. Flock, S. Schulz, Formation and characterization of Fe 3+ -/Cu 2+ -modified zirconium oxide conversion layers on zinc alloy coated steel sheets, Electrochimica Acta (2013), http://dx.
AbstractZirconium oxide conversion layers are considered as environmentally friendly alternatives replacing chromate-based passivation layers in the coil-coating industry. Based on excellent electronic barrier properties they provide an effective corrosion protection of the metallic substrate. In this work, thin layers were grown on HDG-steel-substrates by increasing the local pH at the surface and were characterized using potentiodynamic polarization technique.The influence of Cu(NO 3 ) 2 3H 2 O or Fe(NO 3 ) 3 9H 2 O on morphology and thickness of deposited protective layers were investigated by XPS, ToF-SIMS and FE-SEM. A significant film thickness increase was found by adding Cu 2+ or Fe 3+ ions to the conversion solution. In addition, growth kinetics were studied by in-situ measurements of corrosion potential using potentiodynamic polarization technique.