“…have been recognized to be rich sources also for this group of glycosides. 11-13q28*34*38 As to p-ionone related structures, functionalization of the 5,6-double bond leading to 5,6-epoxy-(17-19), 6-hydroxy- (25,26) and 5,6dihydroxy structures (20,35,36) has been observed. P-Ionone-derived structures, in which the 5,6-double bond was preserved, comprise the 3,4-dihydroxylated compounds 29-32 as well as the P-D-ghcoside 28, the so-called icariside B4, which has been characterized from Epimedium grandifl~rum.~' With compounds 21-24 a few aionone-derived 3-oxygenated glycosides have been reported, including multiple conjugates of the ubiquitous plant constituent vomifoliol 21 (see Figure 2).…”