Study of Intermolecular Interactions in Binary Mixtures of 2-Methoxyaniline with Chlorinated Ethanes at Various Temperatures

Density (ρ), viscosity (η) and ultrasonic velocity (U) of chlorpheniramine with 1-ethanol mixtures are measured in a range of temperatures 303K, 308K and 313K. By using the systematic measurements, various physico chemical quantities, adiabatic compressibility (β), free length (Lf), free volume (Vf), viscous relaxation time (τ) and Gibbs free energy (ΔG) are attained. The deviations of those quantities to their ideal values are derived and revealed with the intermolecular interactions. The standard deviations and the coefficients of Redlich Kister polynomials of excess quantities are also determined to validate the calculations. From these observations, the existence of intermolecular interaction is confirmed and the strength of interactions with the temperatures as 303K>308K>313 K.

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Study of Intermolecular Interactions in Binary Mixtures of 2-Methoxyaniline with Chlorinated Ethanes at Various Temperatures

Cited by 2 publications

References 26 publications

Thermodynamic Studies on Non-ideal Binary Mixtures of Isoamyl Alcohol and Various Alkanols at 298.15 to 308.15 K

Thermodynamic Studies on Non-ideal Binary Mixtures of Isoamyl Alcohol and Various Alkanols at 298.15 to 308.15 K

Intermolecular Interaction between Chlorpheniramine and 1-ethanol at Various Temperatures

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