Self-propulsion of droplets is of
great significance in many fields.
The spontaneous horizontal motion and self-jumping of droplets have
been well realized in various ways. However, there is still a lack
of an effective method to enable a droplet to rotate spontaneously
and steadily. In this paper, by employing an acid droplet and a liquid
metal, the spontaneous and steady rotation of droplets is achieved.
For an acid droplet, it may spontaneously move when it is deposited
on the surface of the liquid metal. By adjusting experimental parameters
to the proper range, the self-rotation of droplet happens. This phenomenon
originates from the fluctuation of the droplet boundary and the collective
movement of bubbles that are generated by the chemical reactions between
the acid droplet and liquid metal. This rotation has a simpler implementation
method and more steady rotation state. Its angular velocity is much
higher than that driven by other mechanisms. Moreover, the movements
of acid droplets on the liquid metal are classified according to experimental
conditions. The internal flow fields, the movements and distribution
of bubbles, and the fluctuation of the droplet boundary are also explored
and discussed. The theoretical model describing the rotational droplet
is given. Our work may deepen the understanding of the physical system
transition affected by chemical reactions and provide a new way for
the design of potential applications, e.g., micro- and nanodevices.