Study of anion adsorption on polycrystalline Pt by electrochemical quartz crystal microbalance

Santos, Mauro C.; Miwa, Douglas Waychi; Machado, Sérgio Antônio Spínola

doi:10.1016/s1388-2481(00)00102-8

Cited by 122 publications

(83 citation statements)

References 21 publications

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“…The curves in Fig. 3 qualitatively resemble those reported in the literature for polycrystalline Pt in sulphuric and perchloric acid solutions [11,19,20]. It is to be mentioned both the NaCl and HCl solutions as the source of Cl − ions gave the similar voltammograms and mass change responses, therefore, no reference is given in Fig.…”

Section: And Eqcm Response Of Ecd Pt In 05 M H 2 So 4 Containing supporting

confidence: 63%

Effect of halogen ions on platinum dissolution under potential cycling in 0.5M H2SO4 solution

Yadav

Nishikata

Tsuru

2007

Electrochimica Acta

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Section: And Eqcm Response Of Ecd Pt In 05 M H 2 So 4 Containing supporting

confidence: 63%

Effect of halogen ions on platinum dissolution under potential cycling in 0.5M H2SO4 solution

Yadav

Nishikata

Tsuru

2007

Electrochimica Acta

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“…The measurement in V-free solution shows the typical potential-frequency curve characteristics known from the literature [30][31][32][33][34][35]. Starting to explain the curve at −0.2 V vs. MMSE, the frequency continuously decreases with rising potential (meaning an increase in electrode mass) due to the build-up of an (hydr)oxide layer at the platinum surface.…”

Section: Electrochemical Quartz Crystal Microbalance Investigationsmentioning

confidence: 89%

Influence of Vanadium Ions on the Degradation Behavior of Platinum Catalysts for Oxygen Reduction Reaction

et al. 2015

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The vanadium air redox flow battery is a combination of a redox flow battery and a reversible fuel cell. For the oxygen reduction during discharge, platinum (Pt) catalysts are common. During operation, vanadium (V) cations can penetrate through a proton exchange membrane into the water/air half-cell. The aim of the present work is to study whether V compounds are deposited on the Pt surface under operation conditions or whether the V ions influence the stability of Pt in any other way. Thereby, bulk platinum electrodes are compared as a simple model system to carbon-supported Pt nanoparticles via cyclic voltammetry. In the case of bulk platinum, electrochemical quartz crystal microbalance measurements showed no deposition of vanadium compounds but indicated the decrease of the (hydr)oxide layer on Pt above V 3+ and VO 2+ redox potentials. Cycling 100 times between oxygen reduction and oxygen evolution potentials with and without a heavy V contamination did not lead to significant degradation of the model catalyst and shows no influence of V ions. On the contrary, the nanoparticle-based catalyst significantly degraded during the same stability protocol. The V contamination lowered the degradation in this case.

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“…(ii) The low solubility of oxygen in phosphoric acid. (iii) The slow diffusion of oxygen through the film of phosphoric acid which covers the platinum catalyst.The adsorption of phosphate by platinum has been studied for more than 30 years 1-15 by means of cyclic voltammetry (CV), [2][3][4][5]9,[11][12][13][14][16][17][18][19][20][21] rotating disc electrode measurements (RDE), [2][3][4][5]8,9,11,13,14 electrochemical impedance spectroscopy (EIS), 13,16,22 transient measurements, 9,23,24 Fourier transform infrared spectroscopy (FTIR), 20,25-27 electrochemical quartz crystal microbalance (QCM), 18 radio tracer experiments, 28 X-ray photoelectron spectroscopy (XPS) 17 and X-ray absorption spectroscopy (XAS). 14,15 The in-operando XAS measurements recently published by Kaserer et al show the adsorption behavior of H 3 PO 4 species on Pt/C fuel cell cathode catalysts in the temperature range of 50-170…”

mentioning

confidence: 99%

2-Sulfoethylammonium Trifluoromethanesulfonate as an Ionic Liquid for High Temperature PEM Fuel Cells

Wippermann

Wackerl

Lehnert

et al. 2015

J. Electrochem. Soc.

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Tafel Oxygen reduction reaction (ORR) in polymer electrolyte fuel cells (PEFC).-High temperature polymer electrolyte fuel cells (HT-PEFCs) are currently based on phosphoric acid-doped polybenzimidazole-type membranes (PBI) and are operated in a temperature range of 120-180• C. HT-PEFCs have several advantages over low temperature PEFCs, such as: easier water and heat management, the possibility of recovering high-grade waste heat, a more compact cooling system and a higher CO tolerance by the anode catalyst.However, a major drawback of HT-PEFCs is the sluggish oxygen reduction reaction (ORR) kinetics in the presence of phosphoric acid. This is primarily caused by three effects: (i) The inhibition effect of phosphoric acid on the ORR because of the poisoning of the Pt catalyst due to the adsorption of the H 3 PO 4 species onto active catalyst sites. (ii) The low solubility of oxygen in phosphoric acid. (iii) The slow diffusion of oxygen through the film of phosphoric acid which covers the platinum catalyst.The adsorption of phosphate by platinum has been studied for more than 30 years 1-15 by means of cyclic voltammetry (CV), [2][3][4][5]9,[11][12][13][14][16][17][18][19][20][21] rotating disc electrode measurements (RDE), [2][3][4][5]8,9,11,13,14 electrochemical impedance spectroscopy (EIS), 13,16,22 transient measurements, 9,23,24 Fourier transform infrared spectroscopy (FTIR), 20,25-27 electrochemical quartz crystal microbalance (QCM), 18 radio tracer experiments, 28 X-ray photoelectron spectroscopy (XPS) 17 and X-ray absorption spectroscopy (XAS). 14,15 The in-operando XAS measurements recently published by Kaserer et al. show the adsorption behavior of H 3 PO 4 species on Pt/C fuel cell cathode catalysts in the temperature range of 50-170• C under the operating conditions of an HT-PEFC. 15In diluted aqueous solutions and at moderate temperatures, sulphuric acid and sulfonic acids like methanesulfonic acid (MSA) or trifluoromethanesulfonic acid (triflic acid, TFMSA) have been found to be less poisonous than phosphoric acid because sulfonate groups are less strongly adsorbed on Pt. 3,29,30 For example, Zelenay et al.,29 in a comparative study of phosphoric acid and TFMSA, showed that * Electrochemical Society Active Member. z E-mail: k.wippermann@fz-juelich.de 0.02 M TFMSA is indeed less strongly adsorbed by comparison to 0.02 M phosphoric acid at room temperature. However, the free space available for oxygen reduction is found to be similar at elevated temperatures and for concentrated solutions. 29 Under these conditions, the advantage of TFMSA lies in its higher oxygen solubility and diffusivity rather than its poisoning effect. 29 Although this result cannot be generalized, it still indicates the importance of oxygen solubility and the diffusion coefficient of oxygen in the electrolyte being used. Proton conducting ionic liquids (PIL).-With respect to alternative electrolytes for HT-PEFCs, proton-conducting ionic liquids (PILs) appear to be suitable, as they do not rely on solvents like water. Moreover...

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Study of anion adsorption on polycrystalline Pt by electrochemical quartz crystal microbalance

Cited by 122 publications

References 21 publications

Effect of halogen ions on platinum dissolution under potential cycling in 0.5M H2SO4 solution

Effect of halogen ions on platinum dissolution under potential cycling in 0.5M H2SO4 solution

Influence of Vanadium Ions on the Degradation Behavior of Platinum Catalysts for Oxygen Reduction Reaction

2-Sulfoethylammonium Trifluoromethanesulfonate as an Ionic Liquid for High Temperature PEM Fuel Cells

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