Studies on Zn(II) and Cd(II) heteroligand complexes with RC(S)NHP(O)(OiPr)2 (R=Ph, NH2, PhNH) and α-diimine (bpy and phen) ligands. C–Cl bond cleavage of CH2Cl2 by [Zn(phen){PhC(S)NP(O)(OiPr)2}2]

Safin, Damir A.; Babashkina, Maria G.; Bolte, Michael; Krivolapov, D. B.; Verizhnikov, Maxim L.; Bashirov, Airat R.; Klein, Axel

doi:10.1016/j.ica.2010.10.001

Cited by 9 publications

(1 citation statement)

References 32 publications

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“…Recently, we have studied the structures of Cd II complexes with [RC(S)NP(X)R′ 2 ] − (X = O, S) ligands. The majority of these structures corresponds to the phosphorylated [RC(S)NP(O)R′ 2 ] − anions. − In contrast to this, only four structures of thiophosphorylated [RC(S)NP(S)R′ 2 ] − anions are known for Cd II . − This is surprising since it has been postulated for a long time that complexes of the dithio derivatives are much more stable compared with those ligands containing oxygen and sulfur atoms simultaneously. Thus, new coordination compounds of [RC(S)NP(S)R′ 2 ] − with Cd II are of great importance and value, especially when considering Cd II complexes of [RC(S)NP(S)R′ 2 ] − as SSPs for CdS nanomaterials.…”

Section: Introductionmentioning

confidence: 99%

CdS Nanoparticles Fabricated from the Single-Source Precursor [Cd{Et₂NC(S)NP(S)(OiPr)₂}₂]: In Depth Experimental and Theoretical Studies

Babashkina

Safin

Mitoraj

et al. 2016

Crystal Growth & Design

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Reaction of the diethylammonium salt of N-thiophosphorylated thioureate [Et 2 NC(S)NP(S)(OiPr) 2 ] − (L − ) with CdCl 2 in aqueous ethanol leads to the complex [CdL 2 ]. The compound crystallizes in the triclinic space group P1̅ with Z = 2 and the metal cation is found in a tetrahedral S 2 S′ 2 coordination environment formed by the C−S and P−S sulfur atoms. The Hirshfeld surface analysis showed that the structure of [CdL 2 ] is dominated by H•••H, S•••H, and O•••H contacts. According to charge and energy decomposition scheme ETS-NOCV, topological noncovalent index (NCI) and quantum theory of atoms in molecules (QTAIM) calculations, both inter-and intramolecular noncovalent C− H•••S and C−H•••H−C interactions are the main factors that stabilize [CdL 2 ].Calculated NMR data, based on the GIAO approach, are in very good agreement with experimental data. The complex [CdL 2 ] is an efficient single-source precursor for the formation of TOPO-capped CdS nanoparticles of about 5 nm diameter with wurtzite structure (TOPO = tri-n-octylphosphine oxide). Their growth was monitored over a period of time by means of UV−vis spectroscopy. From ETS-NOCV modeling, the TOPO molecules were found to strongly adhere to the CdS nanoparticles through dative-covalent Cd−O bonds as well as through secondary noncovalent C−H•••Cd and C−H•••S interactions. The characteristic band edge luminescence was observed in the emission spectra of all samples. The TEM microscopy showed well-dispersed spherical CdS nanoparticles; the composition was supported by EDX.

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Section: Introductionmentioning

confidence: 99%

CdS Nanoparticles Fabricated from the Single-Source Precursor [Cd{Et₂NC(S)NP(S)(OiPr)₂}₂]: In Depth Experimental and Theoretical Studies

Babashkina

Safin

Mitoraj

et al. 2016

Crystal Growth & Design

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Supramolecular Coordination Complexes of theN‐Thiophosphorylated 2,5‐Dithiobiurea [NHC(S)NHP(S)(OiPr)₂]₂with Zn^IIand Cd^IIIons – Cation‐Induced Dinuclear Mesocate Structure versus Tetranuclear Nanoscaled Aggregate

et al. 2014

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The reaction of the deprotonated N‐thiophosphorylated bisthiourea N,N′‐bis(diisopropoxythiophosphorylamidothiocarbonyl)hydrazine {[NHC(S)NHP(S)(OiPr)2]2, H2L} with ZnCl2 leads to the complex [Zn2{[NHC(S)NP(S)(OiPr)2]2}2] ([Zn2L2]), in which two metal cations are each 1,5‐S,S′‐coordinated through the sulfur atoms of the thiocarbonyl and thiophosphoryl groups of the pendant deprotonated thioacylamidothiophosphate functions. The same reaction with CdCl2 leads to the tetranuclear nanoscaled aggregate [(Cd2{[NC(S)NHP(S)(OiPr)2]2}2)2] ([(Cd2L2)2]). This complex contains ligands that are doubly deprotonated through their hydrazine NH groups and exhibit unprecedented μ4 and μ5 coordination modes. DFT calculations have shown that both complexes are stabilized not only by typical coordination bonds (Zn–S, Cd–S) but also by numerous intramolecular “noncovalent” interactions: polar C–H···S and N–H···S, nonpolar C–H···H–C, and σ‐hole bonding (S···S).

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Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)3] ZTO 6H2O and [Cu(phen)3] ZTO 6H2O

Ding

Cao

Zheng

et al. 2018

Chem. Res. Chin. Univ.

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Studies on Zn(II) and Cd(II) heteroligand complexes with RC(S)NHP(O)(OiPr)2 (R=Ph, NH2, PhNH) and α-diimine (bpy and phen) ligands. C–Cl bond cleavage of CH2Cl2 by [Zn(phen){PhC(S)NP(O)(OiPr)2}2]

Cited by 9 publications

References 32 publications

CdS Nanoparticles Fabricated from the Single-Source Precursor [Cd{Et₂NC(S)NP(S)(OiPr)₂}₂]: In Depth Experimental and Theoretical Studies

CdS Nanoparticles Fabricated from the Single-Source Precursor [Cd{Et₂NC(S)NP(S)(OiPr)₂}₂]: In Depth Experimental and Theoretical Studies

Supramolecular Coordination Complexes of theN‐Thiophosphorylated 2,5‐Dithiobiurea [NHC(S)NHP(S)(OiPr)₂]₂with Zn^IIand Cd^IIIons – Cation‐Induced Dinuclear Mesocate Structure versus Tetranuclear Nanoscaled Aggregate

Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)3] ZTO 6H2O and [Cu(phen)3] ZTO 6H2O

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Studies on Zn(II) and Cd(II) heteroligand complexes with RC(S)NHP(O)(OiPr)2 (R=Ph, NH2, PhNH) and α-diimine (bpy and phen) ligands. C–Cl bond cleavage of CH2Cl2 by [Zn(phen){PhC(S)NP(O)(OiPr)2}2]

Cited by 9 publications

References 32 publications

CdS Nanoparticles Fabricated from the Single-Source Precursor [Cd{Et2NC(S)NP(S)(OiPr)2}2]: In Depth Experimental and Theoretical Studies

CdS Nanoparticles Fabricated from the Single-Source Precursor [Cd{Et2NC(S)NP(S)(OiPr)2}2]: In Depth Experimental and Theoretical Studies

Supramolecular Coordination Complexes of theN‐Thiophosphorylated 2,5‐Dithiobiurea [NHC(S)NHP(S)(OiPr)2]2with ZnIIand CdIIIons – Cation‐Induced Dinuclear Mesocate Structure versus Tetranuclear Nanoscaled Aggregate

Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)3] ZTO 6H2O and [Cu(phen)3] ZTO 6H2O

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CdS Nanoparticles Fabricated from the Single-Source Precursor [Cd{Et₂NC(S)NP(S)(OiPr)₂}₂]: In Depth Experimental and Theoretical Studies

CdS Nanoparticles Fabricated from the Single-Source Precursor [Cd{Et₂NC(S)NP(S)(OiPr)₂}₂]: In Depth Experimental and Theoretical Studies

Supramolecular Coordination Complexes of theN‐Thiophosphorylated 2,5‐Dithiobiurea [NHC(S)NHP(S)(OiPr)₂]₂with Zn^IIand Cd^IIIons – Cation‐Induced Dinuclear Mesocate Structure versus Tetranuclear Nanoscaled Aggregate