Studies on the Synthesis of Croomine: Synthesis of the Tricyclic B,C,D-Ring Core Structure<b />

Lindsay, Karl B.; Pyne, Stephen G.

doi:10.1055/s-2004-817773

Synlett

2004

DOI: 10.1055/s-2004-817773

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Studies on the Synthesis of Croomine: Synthesis of the Tricyclic B,C,D-Ring Core Structure

Karl B. Lindsay
¹
,

Stephen G. Pyne
²

Abstract: A convergent and asymmetric synthesis of the tricyclic B,C,D-ring core structure of croomine has been achieved, using aminolysis reactions of chiral vinyl epoxides and the RCM reaction

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6-Hydroxy-5,6-seco-stemocurtisine: A novel seco-stemocurtisine-type alkaloid
Mungkornasawakul
¹
,
Pyne
²
,
Willis
³

et al. 2013
Phytochemistry Letters
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Lie, W. (2013). 6-Hydroxy-5,6-seco-stemocurtisine: a novel seco-stemocurtisine-type alkaloid. Phytochemistry Letters, 6 (4), 602-605.6-Hydroxy-5,6-seco-stemocurtisine: a novel seco-stemocurtisine-type alkaloid AbstractA novel seco-stemocurtisine-type alkaloid, 6-hydroxy-5,6-seco-stemocurtisine was isolated from the aerial parts of Stemona curtisii (Stemonaceae) collected from Trang Province in Thailand. The unprecedented 5,6-seco-pyrido[1,2-a] azepine structure was elucidated by 2D NMR analysis and a single crystal X-ray crystallographic analysis. (C) 2013 Phytochemical Society of Europe. The unprecedented 5,6-seco-pyrido[1,2-a]azepine structure was elucidated by 2D NMR analysis and a single crystal X-ray crystallographic analysis. 6-Hydroxy-5,6-seco-stemocurtisine: A novel seco-stemocurtisine-

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My 37 years of working with nitrogen heterocycles and alkaloids
Pyne
¹

2022
Aust. J. Chem.
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This account highlights work from my laboratory at the University of Wollongong (UOW), concerning nitrogen heterocycles and alkaloids, from my appointment as lecturer in Chemistry in February 1985 to the present time as an Emeritus Professor since 2022. I am thankful to the Royal Australian Chemical Institute for the recognition of my work through the recent award of a Distinguished Fellow at the national conference in Brisbane in July 2022.

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Studies on the Synthesis of Croomine: Synthesis of the Tricyclic B,C,D-Ring Core Structure

Abstract: A convergent and asymmetric synthesis of the tricyclic B,C,D-ring core structure of croomine has been achieved, using aminolysis reactions of chiral vinyl epoxides and the RCM reaction

Cited by 2 publications

References 9 publications

6-Hydroxy-5,6-seco-stemocurtisine: A novel seco-stemocurtisine-type alkaloid

6-Hydroxy-5,6-seco-stemocurtisine: A novel seco-stemocurtisine-type alkaloid

My 37 years of working with nitrogen heterocycles and alkaloids

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