Studies on the oxidative cleavage of the CC triple bond during the autoxidation of acetylenic hydrocarbons. III. Studies on the role of phenylglyoxal in the Autoxidation of Phenylacetylene

Rao, T. S. S.; Pritzkow, W.

doi:10.1002/prac.19873290525

J. Prakt. Chem.

1987

DOI: 10.1002/prac.19873290525

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Studies on the oxidative cleavage of the CC triple bond during the autoxidation of acetylenic hydrocarbons. III. Studies on the role of phenylglyoxal in the Autoxidation of Phenylacetylene

T. S. S. Rao

W. Pritzkow

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Cited by 2 publications

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Studies on the oxidative cleavage of the CC triple bond during the autoxidation of acetylenic hydrocarbons. IV. The reaction of Acyloxy and Alkoxy Radicals with α‐diketones

Rao

Pritzkow

1988

J. Prakt. Chem.

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Dibenzoyl peroxide, diacetyl peroxide and di‐tert‐butyl peroxide were thermally decomposed at 130°C in the presence of benzil, 1‐phenyl‐propane‐1,2‐dione, and 1‐phenyl‐butane‐1,2‐dione using chlorobenzene as the solvent. In all cases benzoic acid was formed. Moreover, from 1‐phenyl‐propane‐1,2‐dione and 1‐phenylbutane‐1,2 dione considerable amounts of benzil were obtained. The results show that reactions of the type (with X· R′O· or X· R′COO·), previously formulated by us to explain the course of the autoxidation of α‐diketones, really take place.

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Studies on the oxidative cleavage of the CC triple bond during the autoxidation of acetylenic hydrocarbons. IV. The reaction of Acyloxy and Alkoxy Radicals with α‐diketones

Rao

Pritzkow

1988

J. Prakt. Chem.

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Ab initio studies of the reactive intermediates involved in the oxidation of acetylenes

Rao

Awasthi

2008

Journal of Molecular Structure: THEOCHEM

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Studies on the oxidative cleavage of the CC triple bond during the autoxidation of acetylenic hydrocarbons. III. Studies on the role of phenylglyoxal in the Autoxidation of Phenylacetylene

Cited by 2 publications

References 7 publications

Studies on the oxidative cleavage of the CC triple bond during the autoxidation of acetylenic hydrocarbons. IV. The reaction of Acyloxy and Alkoxy Radicals with α‐diketones

Studies on the oxidative cleavage of the CC triple bond during the autoxidation of acetylenic hydrocarbons. IV. The reaction of Acyloxy and Alkoxy Radicals with α‐diketones

Ab initio studies of the reactive intermediates involved in the oxidation of acetylenes

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