Studies on the adsorption of Pb(II) from aqueous solutions using sugarcane bagasse-based modified activated carbon with nitric acid: Kinetic, isotherm and desorption
“…6 a) display a wide band within frequency range 3600 to 3000 cm −1 which suggests presence of –NH stretching and –OH bonding of hydroxyl, carboxyl group, and phenol or alcohol groups [ 45 ]. Peaks of preliminary functional groups of the unloaded adsorbent show a relatively broad peak at 3472 and 3415 cm −1 (0-H stretching) [ 51 ], sharp peaks at 2921 cm −1 and a relatively small peak at 2851 cm −1 (C–H stretching alkane) [ 52 ] and a presence of a sharp peak at 1618 cm −1 (C C stretching). The study's observed peaks are consistent with those from results found by both [ 29 , 34 ].…”
“…6 a) display a wide band within frequency range 3600 to 3000 cm −1 which suggests presence of –NH stretching and –OH bonding of hydroxyl, carboxyl group, and phenol or alcohol groups [ 45 ]. Peaks of preliminary functional groups of the unloaded adsorbent show a relatively broad peak at 3472 and 3415 cm −1 (0-H stretching) [ 51 ], sharp peaks at 2921 cm −1 and a relatively small peak at 2851 cm −1 (C–H stretching alkane) [ 52 ] and a presence of a sharp peak at 1618 cm −1 (C C stretching). The study's observed peaks are consistent with those from results found by both [ 29 , 34 ].…”
“…The peak observed at 1260 cm −1 corresponds to the C-O stretching vibration of carboxylic acid and alcohol. 85 The peak at 1032 cm −1 is assigned to the (C-O-C) stretching vibration in cellulose and hemicellulose. 86 The peaks in the range of 400-700 cm −1 are attributed to the Ti-O and Ti-O-Ti stretching vibrations.…”
The ultrasonication supported sorption process is regarded as one of the most innovative and promising methods for removing heavy metal ions from contaminated water.
“…The reusability efficiency of cMGK-HP for Cr(VI) sequestration from aqueous solution was investigated via For the first adsorption experiment, 0.5 g of Cr(VI) ions loaded cMGK-HP was added to 50 mL of 0.1 M HNO 3 solution in a flask for 2 hours at 80°C in order to increase the oxygencontaining functional groups of the regenerated adsorbent. 22 The regenerated cMGK-HP was re-used consecutively for 5 times and the method prescribed by Giri et al 23 was used to calculate the desorption efficiency.…”
Section: Regeneration and Reusability Of Cmgk-hpmentioning
The presence of chromium in industrial wastewater is unavoidable due to its large usage as part of chemical constituents used in many industries. Its removal from wastewater is imperative because it’s toxic in nature. This study investigated the application of NaOH-modified Garcinia kola hull particles (cMGK-HP) for Cr(VI) sequestration from aqueous solution. The optimization of process parameters was executed using Taguchi of Design Expert software for optimum point prediction, analysis of variance, parameters interaction and mathematical model development. A proposed model was used for the adsorption cost analysis. The predicted and experimental percentage of Cr(VI) sequestration were recorded at optimum point to be 99.02% and 98.76% with pH, adsorbent dose, contact time, initial concentration, and temperature of 2, 8 g/L, 20 minutes, 10 mg/L, and 20°C respectively. A correlation coefficient of .9937 between experimental and predicted values of percentage Cr(VI) sequestration affirmed high efficacy of the developed model. ANOVA showed the order of parameter contribution to be pH > adsorbent dose > initial concentration > contact time > temperature. A maximum adsorption capacity of 217.39 mg g−1 was obtained for cMGK-HP. Cost analysis revealed using cMGK-HP to be cost effective for Cr(VI) sequestration with a total operational cost of 0.824 $/mole Cr(VI) ions when compared with commercial activated carbon. Adsorbent characterization revealed the presence of active functional groups enhancing the sequestration process. It could be deduced that cMGK-HP is effective to remove Cr(VI) from solution.
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