We attempt to apply K-Ar dating to extracted smectite from bentonite formations collected by different age formations from Japan, China, and America. The results show that the K-Ar ages of smectite are younger than the expected geological age estimated from the stratigraphic data or other research data. The time differences increase with increased age, and K-Ar ages in this study also increase with increased age. For example, smectite in the old strata of bentonite has an older age than smectite in the young strata. K-Ar dating by smectite has the greatest potential for indicating the crystallized age of smectite.