STUDIES ON PROTEINOGENOUS AMINES. I. THE SYNTHESIS OF Β-Imidazolylethylamine (HISTAMINE).

Koessler, Karl K.; Hanke, Milton Th.

doi:10.1021/ja02244a012

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1946

2011

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Cited by 28 publications

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“…(b) Histidine Albertson and Archer (7) synthesized histidine by the alkylation of acetylaminomalonic ester with 4 (or 5) -chloroimidazole. The latter was prepared from citric acid (188) or from fructose (89,328,329), as indicated below: Snyder et al (164,290,291) and Albertson et al (8,9) prepared tryptophan from aniline via indole (218) and gramine (194) in large quantities and excellent yield. a) Valine, methionine, phenylalanine, tryptophan, histidine, etc.…”

Section: Rcocooh + Nhmentioning

confidence: 99%

The Isolation and Synthesis of the Naturally Occurring a-Amino Acids.

Block¹

1946

Chem. Rev.

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Section: Rcocooh + Nhmentioning

confidence: 99%

The Isolation and Synthesis of the Naturally Occurring a-Amino Acids.

Block¹

1946

Chem. Rev.

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Reaction of 1,3-Disubstituted Acetone Derivatives with Pseudohalides: A Simple Approach to Spiro[4.4]nonane-Type Bis-Oxazolidines and -Imidazolidines (Bicyclic Carbamates, Thiocarbamates, Ureas, and Thioureas)

et al. 2000

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The Nitrosation of Aliphatic Carbon Atoms

Touster

2011

Organic Reactions

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The nitrosation reaction consists in the replacement of a hydrogen atom by the nitroso group with the formation of a nitroso or oximo derivative. With a few exceptions, the replacement of hydrogen on an aliphatic carbon atom requires the presence of an electron‐attracting groups adjacent to the carbon to be nitrosated. Acyl, aroyl, carbonyl, carboxy, carbalkoxyl, nitrogen, cyano, imino, and aryl groups may serve as activators. Monoketones are readily converted into alpha‐oximino ketones, whereas monoesters containing no other activating groups do not undergo the reaction. Victor Meyer discovered the reaction in 1873–1874.

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STUDIES ON PROTEINOGENOUS AMINES. I. THE SYNTHESIS OF Β-Imidazolylethylamine (HISTAMINE).

Cited by 28 publications

References 0 publications

The Isolation and Synthesis of the Naturally Occurring a-Amino Acids.

The Isolation and Synthesis of the Naturally Occurring a-Amino Acids.

Reaction of 1,3-Disubstituted Acetone Derivatives with Pseudohalides: A Simple Approach to Spiro[4.4]nonane-Type Bis-Oxazolidines and -Imidazolidines (Bicyclic Carbamates, Thiocarbamates, Ureas, and Thioureas)

The Nitrosation of Aliphatic Carbon Atoms

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