Colloidal all-inorganic perovskite nanocrystals (PNCs), possessing unique optical properties, have attracted considerable attention in the field of semiconductor nanocrystals (NCs), but their application is hindered by the stability issue resulting partly from dynamic capping ligand binding. Herein, we report a simple method for the synthesis of all-inorganic cesium lead-based (CsPbX 3 ) NCs with enhanced structural stability and photoluminescence quantum yield. Aluminum distearate (AlDS) was introduced into the preparation of CsPbX 3 NCs, on the basis that the surface defects of CsPbX 3 NCs are passivated to form a protective layer on the CsPbX 3 NC surface simultaneously. Benefiting from surface modification, the resistance of the CsPbX 3 NC dispersion against ethanol, ultraviolet irradiation, and heat treatment was enhanced effectively. Moreover, the photoluminescence intensity and stability of the AlDS-modified NC-based films displayed functional superiority to those of pristine NC-based films.