In recent years, special attention has been paid to studying the properties of hydrophobic surfaces of textile materials. The authors provide an overview of the applied textile-processing chemicals and of the methods for imparting hydrophobic properties to textile materials. According to the analysis, it was found that water-and splash-proofing treatment occupies an important place in the finishing processes of textile materials, contributing to a change in their characteristics. The purpose of the research is the development of hydrophobic textile materials for the work clothes production. The aqueous solution based on organosilicon compounds was used for textiles hydrophobization with retention of their performance and hygienic characteristics. The research results of the effect of aqueous solutions based on silane (A-1100 and A-187 trademarks) on the hydrophobic characteristics of textile materials is presented in the article.