Studies of the Coriolis coupling effect on reaction dynamics of ${\rm{H}}({}^{2}{\rm{S}})+{\rm{O}}{{\rm{H}}}^{+} \rightarrow {\rm{O}}({}^{3}{\rm{P}})+{{\rm{H}}}_{2}^{+}({{\rm{{\rm X}}}}^{2}{{\rm{\Sigma }}}_{{\rm{g}}}^{+})$ using the time dependent wave packet method

Abstract

The time dependent wave packet method is employed to study the reaction on a novel potential energy surface (Phys. Chem. Chem. Phys. 2014 16 23594). Both the centrifugal sudden approximation and Coriolis coupling (CC) effect are utilized to calculate the reaction probabilities and integral cross sections. By comparing the results, it is demonstrated that the CC effect does play a vital role in this reaction.