Studies of polystyrene-polybutadiene blend system by inverse gas chromatography

Farooque, A. Mohammed; Deshpande, D. D.

doi:10.1016/0032-3861(92)90052-x

Cited by 41 publications

(36 citation statements)

References 22 publications

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“…Starting form the Flory-Huggins expression for the change of the free enthalpy in mixing, which was extended to three-component systems, they proposed a method of analysis of IGC measurements on polymer blends which yielded the polymer-polymer interaction parameter  ' 23 . They also observed probe dependency and tried to develop a method to evaluate probe-independent interaction [Farooque et al, 1992]. …”

Section: Flory-huggins Parametersmentioning

confidence: 99%

Inverse Gas Chromatography in Characterization of Composites Interaction

Milczewska¹,

Voelkel²

2012

Advanced Gas Chromatography - Progress in Agricultural, Biomedical and Industrial Applications

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Section: Flory-huggins Parametersmentioning

confidence: 99%

Inverse Gas Chromatography in Characterization of Composites Interaction

Milczewska¹,

Voelkel²

2012

Advanced Gas Chromatography - Progress in Agricultural, Biomedical and Industrial Applications

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“…There were a lot of attempts to solve the problem [27][28][29] of so-called "probe dependence" of polymer-polymer interaction and to develop a method to evaluate the probe-independent interaction.…”

Section: Theoreticalmentioning

confidence: 99%

Properties of materials as determined by inverse gas chromatography

Voelkel¹,

Adamska²

2009

Annales UMCS, Chemistry

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“…Difficulties arise however, in that x 0 2;3 can vary with the selection of the vapour probe. This problem has been the subject of much discussion [64,70,71,[100][101][102]. Shi and Shreiber [70] state that the probe dependence of x 2,3 is due to two major contributing factors.…”

Section: The Use Of Igc For the Determination Of Flory-huggins Interamentioning

confidence: 99%

Analysis of interactions in multicomponent polymeric systems: The key-role of inverse gas chromatography

Santos

Guthrie

2005

Materials Science and Engineering: R: Reports

107

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The properties of a polymeric system are a consequence of the interactions that occur between the various components of these complex systems. These components may vary significantly in terms of chemical nature (e.g. organic/inorganic), physical properties (e.g. particle size, surface area, molecular weight), structural characteristics and proportion in the formulations composition. This review paper addresses the major approaches in use regarding the analysis of the interactions that occur between the polymeric system components and the use of such approaches in the interpretation of the chemical, physical and thermodynamic properties of these systems. Special attention is given to the technique of inverse gas chromatography.A case study is presented, where use was made of inverse gas chromatography to characterize thermodynamically the surface of the major components of pigmented PC/PBT blends. The concept of Lewis acidity/basicity was used in the interpretation of the intermolecular interactions nature and potential in these blends, as encountered in phase separation and phase preferences phenomena and as expressed in the morphology, the physical and the mechanical properties of these commercially important composites. #

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Studies of polystyrene-polybutadiene blend system by inverse gas chromatography

Cited by 41 publications

References 22 publications

Inverse Gas Chromatography in Characterization of Composites Interaction

Inverse Gas Chromatography in Characterization of Composites Interaction

Properties of materials as determined by inverse gas chromatography

Analysis of interactions in multicomponent polymeric systems: The key-role of inverse gas chromatography

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