Studies of acyl and thioacyl isocyanates—XII

Tsuge, Otohiko; Sakai, Kentaro; Tashiro, Masashi

doi:10.1016/0040-4020(73)80134-6

Cited by 18 publications

(1 citation statement)

References 12 publications

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“…To the solution of fullerene (129.4 mg, 0.180 µmol) in toluene (125 mL) was added the solution of dimethylsulfonium (ethoxycarbonyl)methylide [4] (36.2 mg, 0.244 mmol) in toluene (12.4 mL) with a cannula. The reaction mixture was stirred at r.t. under Ar for 4 h and then passed through silica gel chromatography eluted with toluene.…”

Section: -Cooet (8)mentioning

confidence: 99%

Single-Molecule Study on Intermolecular Interaction between C₆₀and Porphyrin Derivatives: Toward Understanding the Strength of the Multivalency

Zhang

Yu²,

Jiang³

et al. 2009

Langmuir

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Multivalency is important in molecular self-assembly, although it remains a challenge to correlate the single-molecule results with the multivalent interaction. As the first example, we have combined a well-defined self-assembling system with AFM-based single-molecule force spectroscopy (SMFS) to investigate the intermolecular interactions and multivalency between C(60) and porphyrin derivatives. Compared with the interaction between C(60) and a single porphyrin (29 pN), SMFS has revealed that porphyrin tweezers can provide an enhanced binding interaction with C(60), resulting in a more than 2-fold higher unbinding force (75 pN, at the same loading rate). In addition, a much lower dissociation rate and a shorter effective distance between the bound state and transition state of the interaction are indicated by dynamic force spectroscopy. These results provide new quantitative information on the divalency effect in the unbinding process of C(60) and porphyrin tweezers at the single-molecule level, which is of significance in understanding the strength of the multivalency in the molecular assembly.

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Section: -Cooet (8)mentioning

confidence: 99%