1960
DOI: 10.1021/ja01489a021
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Studies Involving Isotopically Labeled Formic Acid and its Derivatives.1,2 V. Studies of the Decarbonylation of Formic, Benzoylformic and Triphenylacetic Acids in Sulfuric Acid

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Cited by 43 publications
(4 citation statements)
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“…It leads to the conclusion that the reduction of FA proceeds through intermediates formed during this process. According to literature data the mechanism of decarbonylation of FA is as follows:…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…It leads to the conclusion that the reduction of FA proceeds through intermediates formed during this process. According to literature data the mechanism of decarbonylation of FA is as follows:…”
Section: Resultsmentioning
confidence: 99%
“…It leads to the conclusion that the reduction of FA proceeds through intermediates formed during this process. According to literature data 11,30 the mechanism of decarbonylation of FA is as follows: The dependence of the rate of reduction on both cathodic potential and concentration of FA suggested that mixed kinetics was followed. Namely, a slow charge transfer and slow diffusion process take place simultaneously.…”
Section: Mechanismmentioning
confidence: 99%
“…Although not usually classified as "organic", carbon monoxide (CO) is reduced relative to CO 2 , with carbon in the same oxidation state as in formic acid (HCOOH), which is a bona f ide organic. HCOOH is known to dehydrate in concentrated (>85%) H 2 SO 4 to give CO. 13,14 Literature over the past 50 years has, with a few exceptions, 15 discounted organics as relevant to Venus as a target for observation, under the view that these would be destroyed by concentrated sulfuric acid. For example, Dayhoff and Sagan wrote that "[t]here can be no free carbon, hydrocarbons, formaldehyde, or any other organic molecule present in more than trace amounts" above Venus.…”
Section: Introductionmentioning
confidence: 99%
“…Although not usually classified as “organic”, carbon monoxide (CO) is reduced relative to CO 2 , with carbon in the same oxidation state as in formic acid (HCOOH), which is a bona fide organic. HCOOH is known to dehydrate in concentrated (>85%) H 2 SO 4 to give CO. , …”
Section: Introductionmentioning
confidence: 99%