1991
DOI: 10.1002/jbm.820251004
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Student research award in the undergraduate, Master candidate category, or health science degree candidate category, 17th annual meeting of the society for biomaterials, scottsdale, AZ may 1–5,1991. Characterization of the interface in the plasma‐sprayed HA coating/Ti‐6Al‐4V implant system

Abstract: The successful use of plasma-sprayed hydroxyapatite (HA) coatings on Ti-alloy implants for implant-to-bone fixation requires strong adherence of the ceramic coating to the underlying metal substrate. In this study, the metal-ceramic interface was evaluated using mechanical, chemical, and structural characterization methods. Evaluations of an HA-coated Ti-6Al-4V implant system using a modified short bar technique for interfacial fracture toughness determination revealed relatively low fracture toughness values.… Show more

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Cited by 227 publications
(18 citation statements)
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“…For example, HA coatings, obtained by PLD, showed greater adherence to a titanium alloy when compared with plasma-sprayed HA coatings (Vasanthan et al 2008). Besides, it might depend on the coating thickness and its chemical composition, namely coatings of 50-μm thick gave higher values of the adhesion strength than those of 240-μm thick (Filiaggi et al 1991), while scratch tests revealed that the sol-gel-fluorinated HA coating adhered to Ti-alloy substrate up to 35% better as the fluorine concentration increased in the coating (Zhang et al 2006). Furthermore, the nature, structure and chemical composition of the substrate surface play an important role.…”
Section: Reviewmentioning
confidence: 99%
“…For example, HA coatings, obtained by PLD, showed greater adherence to a titanium alloy when compared with plasma-sprayed HA coatings (Vasanthan et al 2008). Besides, it might depend on the coating thickness and its chemical composition, namely coatings of 50-μm thick gave higher values of the adhesion strength than those of 240-μm thick (Filiaggi et al 1991), while scratch tests revealed that the sol-gel-fluorinated HA coating adhered to Ti-alloy substrate up to 35% better as the fluorine concentration increased in the coating (Zhang et al 2006). Furthermore, the nature, structure and chemical composition of the substrate surface play an important role.…”
Section: Reviewmentioning
confidence: 99%
“…[158] reported that evaluations of an HA-coated Ti-6Al-4V implant system using a modified short bar technique for interfacial fracture toughness determination revealed relatively low fracture toughness values. Using high resolution electron spectroscopic imaging, evidence of chemical bonding was revealed at the plasma-sprayed HA/Ti-6Al-4V interface, although bonding was primarily due to mechanical interlocking at the interface [158]. The modulus of elasticity, residual stress and strain, bonding strength, and microstructure of the plasma-sprayed hydroxyapatite coating were evaluated on Ti-6Al-4V substrate with and without immersion in Hank’s balanced salt solution.…”
Section: Surface Texturingmentioning
confidence: 99%
“…Adhesion is overwhelmingly provided by mechanical clamping of coating particles to asperities of the roughened surface of the metallic substrate. Despite claims that a thin reaction layer of calcium dititanate (CaTi 2 O 5 ) or calcium titanate (perovskite, CaTiO 3 ) exists that will mediate adhesion [35][36][37], experimental evidence of such a reaction layer in as-sprayed coatings is scant or absent. Owing to its thinness, visualization by transmission electron microscopy even at high magnification [20] is hampered by its exiguity owing to the very short diffusion paths of Ca 2+ and Ti 4+ ions, respectively, that render any potential reaction zone extremely thin.…”
Section: Adhesion Strengthmentioning
confidence: 99%