Structures of indium trichloride complexes with 2,2′-bipyridyl. Stereochemical features of pseudo-octahedral indium(III) complex halides

Group 13 complexes of dipyridylmethane, a forgotten ligand in coordination chemistry

“…For example, (bpy)InCl3•H2O has been prepared from InCl3 and bpy in aqueous conditions. 28 The + that is structurally similar to that in 2c. 31 The compound was synthesized 35 ligand non-innocence is also a prominent feature in main group chemistry of bpy and that of group 13 elements in particular.…”

Trichlorido(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)(methanol-κO)indium(III)

“…Yousefi, Khalighi et al (2008). For related structures, see: Ilyukhin & Malyarick (1994); Malyarick et al (1992); Nan et al (1987); Ahmadi, Kalateh, Abedi et al (2008).…”

“…[Fe(phen)Cl 3 (DMSO)], (XI), (Amani et al, 2007) and [Fe(phen)Cl 3 (CH 3 OH)].CH 3 OH, (XII), (Khavasi et al, 2007) [where bipy is 2,2′-bipyridine, DMSO is dimethyl sulfoxide and phen is 1,10-phenanthroline]. There are several (Malyarick et al, 1992), [In(phen)Cl 3 (DMSO)], (XVI), (Nan et al, 1987) (Ilyukhin & Malyarick, 1994) have been synthesized and characterized by single-crystal X-ray diffraction methods. We report herein the synthesis and crystal structure of the title compound, (I).…”

Trichlorido(dimethyl sulfoxide-κO)(di-2-pyridylamine-κ2N,N′)indium(III)

“…For related structures, see: Abedi et al (2011Abedi et al ( , 2012a; Ahmadi et al (2008); Clemente (2005); Dong et al (1987); Ilyuhin & Malyarik (1994); ; Kalateh, Norouzi et al (2008); Malecki et al (2011); Malyarick et al (1992); Shi & Jiang (2006); Shirvan & Haydari Dezfuli (2012); Yoshikawa et al (2004); Yousefi et al (2009).…”

“…Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXTL (Sheldrick, 2008). (Malyarick et al, 1992), [In(phen)Cl 3 (DMSO)], (VI) (Dong et al, 1987), (Ahmadi et al, 2008), [In(5,5′-dmbipy)Cl 3 (MeOH)], (X) (Abedi et al, 2012b) (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline, DMSO = dimethyl sulfoxide, 4,4′-dmbipy = 4,4′-dimethyl-2,2′-bipyridine, 5,5′-dmbipy = 5,5′-dimethyl-2,2′-bipyridine, 4,4′-dtbipy = 4,4′-di-tert-butyl-2,2′-bipyridine, 4bt = 4,4′-bithiazole), have been synthesized and characterized by single-crystal X-ray diffraction methods. Di-2-pyridylamine (DPA) is a good bidentate ligand, and numerous complexes with DPA have been prepared, such as that of [Hg(DPA)Br 2 ], (XIV) (Kalateh, Norouzi et al, 2008), [Hg(DPA)Cl 2 ], (XV) (Yousefi et al, 2009), [Pt(DPA)Cl 4 ].DMF, (XVI) (Abedi et al, 2011), [Ir(DPA) 2 Cl 2 ](PF 6 ), (XVII) (Yoshikawa et al, 2004) (Malecki et al, 2011) and [Au(DPA)Cl 2 ]Cl, (XX) (Shi & Jiang, 2006).…”