Structures and photocatalytic activities of metal-organic frameworks derived from rigid aromatic dicarboxylate acids and flexible imidazole-based linkers

Qu, Hua; Qiu, Ling; Leng, Xiao-Ke; Wang, Miaomiao; Lan, She-Ming; Wen, Lili; Li, Dongfeng

doi:10.1016/j.inoche.2011.05.017

Cited by 41 publications

(10 citation statements)

References 34 publications

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“…However, the same metal-nitrogen bonds also have different values in different coordination geometries. The bond lengths of CdÅ), which is consistent with the fact that bond lengths in a tetrahedral geometry are generally shorter than those in other geometries[37].The flexible N-donor ligands (bbim and bbbm) can freely rotate due to the existence of C-C single bond of -(CH 2 ) 4 -group, forming a series of conformations. For 1, there exist two kinds of trans "S" bbim ligands with different dihedral angles between the two benzimidazole rings.…”

supporting

confidence: 76%

Syntheses, crystal structures and luminescent properties of six new d10 transitional metal coordination polymers based on bis(benzimidazole) ligands

Yang

Luo

et al. 2015

Polyhedron

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supporting

confidence: 76%

Syntheses, crystal structures and luminescent properties of six new d10 transitional metal coordination polymers based on bis(benzimidazole) ligands

Yang

Luo

et al. 2015

Polyhedron

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“…Application of MOCPs as heterogeneous catalysts toward removal of dye contaminants from water has recently attained much attention [32]. To investigate the catalytic behavior of complexes 1-4 in detail, Congo red azo dye was selected as a model dye contaminant to evaluate the efficiency of catalytic degradation.…”

Section: Catalytic Activitymentioning

confidence: 99%

Structural modulation and properties of silver(I) coordination polymers from 2,6-naphthalenedicarboxylic acid and flexible N-donor linkers

Wang

Huang

Dong

et al. 2015

Transition Met Chem

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Based on the N-donor auxiliary ligand effect, four new silver(I) coordination polymers derived from 2,6-naphthalenedicarboxylic acid (H 2 ndc), namely [Ag(L1)-(ndc) 0.5 ] n (1), [Ag(L2)(ndc) 0.5 ] n (2), {[Ag(L3)(ndc) 0.5 ]Á 0.5(H 2 ndc)} n (3), and [Ag(L4)(H 2 O)ÁHndc] n (4) (L1 = 1,3-bis(thiabendazole)butane, L2 = 4,4 0 -bis(pyrazole-1-ylmethyl)-biphenyl, L3 = 1,4-bis(benzimidazole)butane, L4 = 4,4 0 -dipyridylamine), have been synthesized by solvothermal reactions. Complex 1 possesses a 1D infinite loop and chain, which is further extended into a 3D supramolecular framework by p-p stacking interactions. Complex 2 presents an unprecedented 3D (3,4)-connected lim (baa-e-3,4-Imma) topology with the Schläfli symbol of (4.10 2 )2(4 2 .10 4 ). Complex 3 exhibits a 2D three-connected hcb (Shubnikov hexagonal plane) network and the Schläfli symbol is (6 3 ). Complex 4 shows a 1D linear chain, which generates a 2D supramolecular layer via hydrogen bonding interactions. Solid-state properties of 1-4 have also been investigated, which display high thermal stability and intense fluorescent emission in solid state. Moreover, the complexes manifest excellent catalytic activities for the decomposition of Congo red azo dye by hydrogen peroxide in a Fenton-like process.

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“…Here, to study such transformation process in an lucrative manner, we have synthesized five new and one previously reported ( 3 ) , mixed ligand metal–organic frameworks, namely, {[Cd(1,4-bib)(glut)]·(4H 2 O)} n ( 1 ), {[Zn(1,4-bib)(glut)]·(4H 2 O)} n ( 2 ), {[Co(1,4-bib)(3,5-pydc)]·(2H 2 O)} n ( 3 ), {[Mn(1,4-bib)(3,5-pydc)]·(2H 2 O)} n ( 4 ), {[Zn(1,4-bib)(3-mglut)]·(4H 2 O)} n ( 5 ), and {[Zn(1,4-bib)(2,2′-dmglut)]·(2H 2 O)} n ( 6 ) from 1-(4-(1 H -imidazole-1-yl)butyl)-1 H -imidazole (1,4-bib) using four different acids salt, disodium glutarate (Na 2 glut), pyridine-3,5-dicarboxylate (3,5-pydc), 3-methyl glutarate (3-mglut) and 2,2′-dimethyl glutarate (Na 2 2,2′-dmglut), and four different metal ions. All compounds have been characterized by single-crystal X-ray diffraction, powder X-ray diffraction, and other physicochemical methods.…”

Section: Introductionmentioning

confidence: 99%

Crystalline to Crystalline Phase Transformations in Six Two-Dimensional Dynamic Metal–Organic Frameworks: Syntheses, Characterizations, and Sorption Studies

Haque

Halder

Ghoshal

2018

Crystal Growth & Design

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Six dynamic metal–organic frameworks, namely, {[Cd(1,4-bib)(glut)]·(4H2O)} n (1), {[Zn(1,4-bib)(glut)]·(4H2O)} n (2), {[Co(1,4-bib)(3,5-pydc)]·(2H2O)} n (3), {[Mn(1,4-bib)(3,5-pydc)]·(2H2O)} n (4), {[Zn(1,4-bib)(3-mglut)]·(4H2O)} n (5), and {[Zn(1,4-bib)(2,2′-dmglut)]·(2H2O)} n (6) from 1-(4-(1H-imidazole-1-yl)butyl)-1H-imidazole (1,4-bib) using four different dicarboxylic acids salt [disodium glutarate (Na2glut), pyridine-3,5-dicarboxylate (3,5-pydc), 3-methyl glutarate (3-mglut), 2,2′-dimethyl glutarate (Na22,2′-dmglut)], and four different divalent transition metal ions have been synthesized. Out of these, the structure of compound 3 has been previously reported although synthesized in different method, whereas the rest of the compounds are new. All of these synthesized compounds are characterized by single crystal and powder X-ray diffraction and other physicochemical methods. All the compounds exhibit 2D structure as evident by single crystal X-ray studies. Interestingly, all of these compounds show crystalline to crystalline phase transformation. Variable temperature PXRD study indicates compounds 1 and 6 show single-step phase transformation and the rest show two-step phase transformation upon desolvation. All of these transformations have also been established by IR spectroscopy. Among the structural transformations listed, 1–5 show reversible crystalline to crystalline phase transformation on desolvation and resolvation, whereas 6 shows an irreversible transformation. All of these transformations are thoroughly investigated by PXRD and IR spectroscopy. Sorption studies with CO2 and N2 were also performed for all the metal–organic frameworks and characteristic surface adsorptions are found in all the cases.

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Structures and photocatalytic activities of metal-organic frameworks derived from rigid aromatic dicarboxylate acids and flexible imidazole-based linkers

Cited by 41 publications

References 34 publications

Syntheses, crystal structures and luminescent properties of six new d10 transitional metal coordination polymers based on bis(benzimidazole) ligands

Syntheses, crystal structures and luminescent properties of six new d10 transitional metal coordination polymers based on bis(benzimidazole) ligands

Structural modulation and properties of silver(I) coordination polymers from 2,6-naphthalenedicarboxylic acid and flexible N-donor linkers

Crystalline to Crystalline Phase Transformations in Six Two-Dimensional Dynamic Metal–Organic Frameworks: Syntheses, Characterizations, and Sorption Studies

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