Structure-property relationship and transport properties of structurally related silyl carbonate electrolytes

Polyethers as Complexing Agents in Calcium-Catalyzed Cyclic Carbonate Synthesis

“…The furfuryl moiety can be produced from renewables, and the epoxide 3g based on the furfuryl building block was successfully converted to yield the corresponding carbonate 4g in 99% yield. Silyl-functionalized carbonates find wide applications in industry since they have potential application possibilities as electrolytes, , for surface modification, and as precursors for the synthesis of nonisocyanate polyhydroxyurethane hybrid materials. − In this catalytic system the silyl-functionalized carbonate 4h was isolate in 99% yield. Also, the highly fluorinated carbonates 4i can be used as electrolytes in lithium batteries. , Under our standard conditions, 57% yield of 4i could be generated.…”

A robust and porous titanium metal–organic framework for gas adsorption, CO2capture and conversion

“…29 The capture and conversion of CO 2 into valuable chemicals has been a research hotspot. 30 Cyclic carbonates are very important chemicals that can be used as polar aprotic solvents for synthetic and catalytic applications, 31,32 electrolyte components in lithium batteries, 33,34 monomers for polyurethanes and polycarbonates, 35,36 and fine chemical intermediates. 37,38 In particular, the synthesis of cyclic carbonates via the cycloaddition of CO 2 into epoxides is a primary target for industrial applications.…”

Formation of Value-Added Cyclic Carbonates by Coupling of Epoxides and CO2by Ruthenium Pincer Hydrazone Complexes under Atmospheric Pressure

“…CO 2 , discharged from anthropogenic activities, is a crucial component of greenhouse gas and causes serious environmental distress. , Near-real-time data direct that worldwide CO 2 production recovered by 4.8% in 2021 will reach 34.9 Gt CO 2 after falling to record-low levels in 2020 due to CO 2 emissions from industrial operations and energy combustion increasing to their highest annual level in 2021 . Therefore, along with the direct, reliable, and most effective way of the direct reduction of CO 2 from the atmosphere, CO 2 reduction, − CO 2 insertion to form cyclic carbonates through CO 2 to epoxide cycloaddition is a desirable and 100% atom-economical approach. − The resulting cyclic organic carbonates with a five-membered ring have a wide range of uses, including those of electrolytes, fine chemicals, building blocks for synthetic polymers, solvents, and industrial lubricants. − …”