Abstract:Boron-based additives are currently the mainstream filmforming additives. They generate B−F-containing species and then participate in the formation of the cathode−electrolyte interphase (CEI) film. However, little is known about their oxidative decomposition mechanisms, reaction processes, and the relationship between their molecular structure and interface stability in electrolyte. Here, the reaction mechanisms and processes of trimethyl borate (TMB) with fluorides (F − , PF 6 − , HF, and PF 5 ) in electroly… Show more
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