Structure of Λ(δλλ)-[Co(en)3]I3(I)2

Kollitz, M.R.; Oliver, Allen G.; Lappin, A. Graham

doi:10.1107/s2056989021002826

Acta Cryst E

2021

DOI: 10.1107/s2056989021002826

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Structure of Λ(δλλ)-[Co(en)₃]I₃(I)₂

M.R. Kollitz¹,

Allen G. Oliver²,

A. Graham Lappin³

Abstract: The structure of tris(ethane-1,2-diamine-κ2 N,N')cobalt(III) bis(iodide) triiodide, [Co(C2H8N2)3]I3(I)2, at 120 K has orthorhombic (P212121) symmetry. The diamine nitrogen atoms form N—H...I hydrogen bonds throughout the lattice, resulting in a three-dimensional network, which involves the iodide and all atoms in the triiodide anions.

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2022

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Insight into the Stereocontrol of DNA Polymerase‐Catalysed Reaction by Chiral Cobalt Complexes

et al. 2022

Adv Synth Catal

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Enantiomers of chiral substances typically have distinct biological activities, thus, the explorations of biochemical processes at the enantiomeric level has very high significance. This study investigated DNA polymerase-catalyzed reaction modulated by various types of chiral cobalt complexes. The experimental data showed that polymerase reactions were inhibited or accelerated in the presence of KMore importantly, the stereocontrol of bioreactivity was found to be different for the enantiomers, which was reflected in their ability to bind to the polymerase reaction system. The docking simulation illustrated that the acceleration or inhibition of polymerase reaction could be correlated with diverse electrostatic energy induced by the attached metal chelates, whereas the different stereocontrol of bioreactivity for the enantiomers was attributed to a discrepancy of Van der Waals interactions between the enantiomer and polymerase catalytic sites.

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Insight into the Stereocontrol of DNA Polymerase‐Catalysed Reaction by Chiral Cobalt Complexes

et al. 2022

Adv Synth Catal

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show abstract

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Structure of Λ(δλλ)-[Co(en)₃]I₃(I)₂

Cited by 1 publication

References 18 publications

Insight into the Stereocontrol of DNA Polymerase‐Catalysed Reaction by Chiral Cobalt Complexes

Insight into the Stereocontrol of DNA Polymerase‐Catalysed Reaction by Chiral Cobalt Complexes

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