Abstract:Luminescence due to the d-f transition of Ce 3+ is quite rare in metal-organic complexes where concentrate quenching frequently occurs. One of the possible ways to avoid this is to design an architecture with elongated metal-metal distances. In the structure of the title complex, triaquatris(1,1,1-trifluoro-4-oxopentan-2-olato-complex is linked to neighbouring ones by hydrogen bonding. Within the complex, the Ce III atom is coordinated by nine O atoms from three 1,1,1-trifluoro-4-oxopentan-2-olate (tfa) anions… Show more
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