Structure of sodium methanesulfonate

Wei, Chin Hsuan; Hingerty, B.E.

doi:10.1107/s056774088100784x

Cited by 26 publications

(24 citation statements)

References 18 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The geometrical parameters of the CH 3 SO 3 − anions: the S\ \C and S\ \O bond lengths and values of the C-S-O angles are very close to the corresponding parameters observed in the sodium methanesulfonate salt [24]. But observed diversity of the values of the O-S-O angles in titled crystal arises from hydrogen bonds in which the -SO 3 residue of the methanesulfonic anion is involved ( Table 2).…”

Section: Crystal Structure Descriptionsupporting

confidence: 62%

Vibrational, XRD and 13 C NMR studies of DL-phenylglycinium methanesulfonate crystal

Wołoszyn

Ilczyszyn

Haupa

2016

Spectrochimica Acta Part A: Molecular and Biomolecular Spectros

View full text Add to dashboard Cite

Section: Crystal Structure Descriptionsupporting

confidence: 62%

Vibrational, XRD and 13 C NMR studies of DL-phenylglycinium methanesulfonate crystal

Wołoszyn

Ilczyszyn

Haupa

2016

Spectrochimica Acta Part A: Molecular and Biomolecular Spectros

View full text Add to dashboard Cite

“…In both structures the methanesulfonate ion lies on a mirror plane, so has C s symmetry; however, the molecular symmetry is close to C 3v . Otherwise, the methanesulfonate ion is unremarkable, the molecular geometry is very similar to that found in Na(CH 3 SO 3 ) [24] and Cs(CH 3 SO 3 ) [25].…”

Section: Structural Studiessupporting

confidence: 55%

Structure and vibrational spectroscopy of lithium and potassium methanesulfonates

Parker

Revill-Hivet²,

Nye

et al. 2020

R. Soc. open sci.

View full text Add to dashboard Cite

In this work, we have determined the structures of lithium methanesulfonate, Li(CH 3 SO 3 ), and potassium methanesulfonate, K(CH 3 SO 3 ), and analysed their vibrational spectra. The lithium salt crystallizes in the monoclinic space group C 2/ m with two formula units in the primitive cell. The potassium salt is more complex, crystallizing in I 4/ m with 12 formula units in the primitive cell. The lithium ion is fourfold coordinated in a distorted tetrahedron, while the potassium salt exhibits three types of coordination: six-, seven- and ninefold. Vibrational spectroscopy of the compounds (including the 6 Li and 7 Li isotopomers) confirms that the correlation previously found, that in the infrared spectra there is a clear distinction between coordinated and not coordinated forms of the methanesulfonate ion, is also valid here. The lithium salt shows a clear splitting of the asymmetric S–O stretch mode, indicating a bonding interaction, while there is no splitting in the spectrum of the potassium salt, consistent with a purely ionic material.

show abstract

“…CaA C H T U N G T R E N N U N G (CH 3 SO 3 ) 2 . [6][7][8] BaA C H T U N G T R E N N U N G (CH 3 SO 3 ) 2 has only been characterized by means of powder diffraction, so only the lattice parameters have been reported, which showed that the compound is not isotypic with its Ca congener. [9] The few anhydrous transition metal methanesulfonates are AgA C H T U N G T R E N N U N G (CH 3 SO 3 ) and Hg 2 A C H T U N G T R E N N U N G (CH 3 SO 3 ) 2 , [10,11] and simple binary rare earth metal methanesulfonates are LaA C H T U N G T R E N N U N G (CH 3 SO 3 ) 3 and YbA C H T U N G T R E N N U N G (CH 3 SO 3 ) 3 .…”

Section: So 3 ) Csa C H T U N G T R E N N U N G (Ch 3 So 3 ) Andmentioning

confidence: 99%

Methanesulfonates of High‐Valent Metals: Syntheses and Structural Features of MoO₂(CH₃SO₃)₂, UO₂(CH₃SO₃)₂, ReO₃(CH₃SO₃), VO(CH₃SO₃)₂, and V₂O₃(CH₃SO₃)₄ and Their Thermal Decomposition under N₂ and O₂ Atmosphere

Betke

Neuschulz

Wickleder

2011

Chemistry A European J

View full text Add to dashboard Cite

Oxide methanesulfonates of Mo, U, Re, and V have been prepared by reaction of MoO(3), UO(2)(CH(3)COO)(2)·2H(2)O, Re(2)O(7)(H(2)O)(2), and V(2)O(5) with CH(3)SO(3)H or mixtures thereof with its anhydride. These compounds are the first examples of solvent-free oxide methanesulfonates of these elements. MoO(2)(CH(3)SO(3))(2) (Pbca, a=1487.05(4), b=752.55(2), c=1549.61(5) pm, V=1.73414(9) nm(3), Z=8) contains [MoO(2)] moieties connected by [CH(3)SO(3)] ions to form layers parallel to (100). UO(2)(CH(3)SO(3))(2) (P2(1)/c, a=1320.4(1), b=1014.41(6), c=1533.7(1) pm, β=112.80(1)°, V=1.8937(3) nm(3), Z=8) consists of linear UO(2)(2+) ions coordinated by five [CH(3)SO(3)] ions, forming a layer structure. VO(CH(3)SO(3))(2) (P2(1)/c, a=1136.5(1), b=869.87(7), c=915.5(1) pm, β=113.66(1)°, V=0.8290(2) nm(3), Z=4) contains [VO] units connected by methanesulfonate anions to form corrugated layers parallel to (100). In ReO(3)(CH(3)SO(3)) (P1, a=574.0(1), b=1279.6(3), c=1641.9(3) pm, α=102.08(2), β=96.11(2), γ=99.04(2)°, V=1.1523(4) nm(3), Z=8) a chain structure exhibiting infinite O-[ReO(2)]-O-[ReO(2)]-O chains is formed. Each [ReO(2)]-O-[ReO(2)] unit is coordinated by two bidentate [CH(3)SO(3)] ions. V(2)O(3)(CH(3)SO(3))(4) (I2/a, a=1645.2(3), b=583.1(1), c=1670.2(3) pm, β=102.58(3), V=1.5637(5) pm(3), Z=4) adopts a chain structure, too, but contains discrete [VO]-O-[VO] moieties, each coordinated by two bidentate [CH(3)SO(3)] ligands. Additional methanesulfonate ions connect the [V(2)O(3)] groups along [001]. Thermal decomposition of the compounds was monitored under N(2) and O(2) atmosphere by thermogravimetric/differential thermal analysis and XRD measurements. Under N(2) the decomposition proceeds with reduction of the metal leading to the oxides MoO(2), U(3)O(7), V(4)O(7), and VO(2); for MoO(2)(CH(3)SO(3))(2), a small amount of MoS(2) is formed. If the thermal decomposition is carried out in a atmosphere of O(2) the oxides MoO(3) and V(2)O(5) are formed.

show abstract

Structure of sodium methanesulfonate

Cited by 26 publications

References 18 publications

Vibrational, XRD and 13 C NMR studies of DL-phenylglycinium methanesulfonate crystal

Vibrational, XRD and 13 C NMR studies of DL-phenylglycinium methanesulfonate crystal

Structure and vibrational spectroscopy of lithium and potassium methanesulfonates

Methanesulfonates of High‐Valent Metals: Syntheses and Structural Features of MoO₂(CH₃SO₃)₂, UO₂(CH₃SO₃)₂, ReO₃(CH₃SO₃), VO(CH₃SO₃)₂, and V₂O₃(CH₃SO₃)₄ and Their Thermal Decomposition under N₂ and O₂ Atmosphere

Contact Info

Product

Resources

About

Structure of sodium methanesulfonate

Cited by 26 publications

References 18 publications

Vibrational, XRD and 13 C NMR studies of DL-phenylglycinium methanesulfonate crystal

Vibrational, XRD and 13 C NMR studies of DL-phenylglycinium methanesulfonate crystal

Structure and vibrational spectroscopy of lithium and potassium methanesulfonates

Methanesulfonates of High‐Valent Metals: Syntheses and Structural Features of MoO2(CH3SO3)2, UO2(CH3SO3)2, ReO3(CH3SO3), VO(CH3SO3)2, and V2O3(CH3SO3)4 and Their Thermal Decomposition under N2 and O2 Atmosphere

Contact Info

Product

Resources

About

Methanesulfonates of High‐Valent Metals: Syntheses and Structural Features of MoO₂(CH₃SO₃)₂, UO₂(CH₃SO₃)₂, ReO₃(CH₃SO₃), VO(CH₃SO₃)₂, and V₂O₃(CH₃SO₃)₄ and Their Thermal Decomposition under N₂ and O₂ Atmosphere