Structure of lithium 1-pyrrolidinecarbodithioate tetrahydrate, Li.C5H8NS2.4H2O

Ymén, I.

doi:10.1107/s0108270183005491

Cited by 4 publications

(3 citation statements)

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“…Li-O distances may also be compared with values reported for the homoleptic parent hydroxylic LiO 4 coordination array as found in [Li(OH 2 ) 4 ] ϩ , but, regrettably, the spread of such values, presumably because of more potent hydrogen-bonding effects, tends to be rather large, e.g. in the two precise studies of dithiocarbamate salts [5], Li-O distances range between 1.907Ϫ1.954(5) (< > 1.93(3)) and 1.906Ϫ2.000(3) (< > 1.93(4)); < > overall 1.93(3) Å ). The crystal packings are of considerable interest.…”

Section: Resultsmentioning

confidence: 99%

The Structural Characterization of some t‐Butanol Solvates of some Lithium Halides, of LiX : ^tBuOH(1 : 4,6) Ratio

Buttery

Plackett

Skelton³

et al. 2006

Zeitschrift anorg allge chemie

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The single crystal structural characterization of an array of t-butanol solvates of the lithium halides LiX, X ϭ Cl, Br, I is recorded. Two series have been identified, of LiX : t BuOH ratio 1:4 and 1:6, represented by the formulations [Li(HO t Bu) 4 ]X (X ϭ Cl, I; not isomorphous) and [Li(HO t Bu) 4 ]X·2 t BuOH (all X ϭ Cl, Br, I, also BH 4 ); isomorphous, triclinic P1, a ϳ 10.3, b ϳ 13, c ϳ 14.4 Å , α ϳ 73, β ϳ 70, γ ϳ 68°, Z ϭ 2. Li-O are 1.97 Å , in an environment of quasi-42m symmetry, the pair of O-Li-O angles trans to each other which contain the hydroxyl hydrogen atoms

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Section: Resultsmentioning

confidence: 99%

The Structural Characterization of some t‐Butanol Solvates of some Lithium Halides, of LiX : ^tBuOH(1 : 4,6) Ratio

Buttery

Plackett

Skelton³

et al. 2006

Zeitschrift anorg allge chemie

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“…No interaction has been found between Li+ and sulfur atoms. [19][20][21][22] Interactions between Li+ and oxygen donor atoms (hard base) are strong while those with the softer nitrogen atoms are weaker. The classification of hard and soft bases is shown in Table II.…”

Section: Coordination Sites In Ll+-ligand Complexesmentioning

confidence: 99%

“…Model structures of these ligands show that their participation in TBP geometry is unfavorable. All of the cyclic polyethers having four ethereal oxygens (15,22,38,41) provide the square basis for 5-fold SP coordination. 179 The coordination number and geometry around the Li+ is dictated by the ligand.…”

Section: Lhhlum-selectlve Ionophoresmentioning

confidence: 99%

Coordination chemistry of lithium ion: a crystal and molecular structure review

Olsher¹,

Izatt²,

Bradshaw³

et al. 1991

Chem. Rev.

362

185

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Comparative analysis of M–O, M–S and cation–π(arene) interactions in the alkali metal (Na+, K+, Rb+, Cs+) bis-dithiocarbamate salts of N,N′-dibenzyl-1,2-ethylenediamine

et al. 2009

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The alkali metal (Na + , K + , Rb + , Cs + ) bis-dithiocarbamate (bis-dtc) salts of N,N 0 -dibenzyl-1,2ethylenediamine have been prepared from the reaction of N,N 0 -dibenzyl-1,2-ethylenediamine with carbon disulfide in the presence of two equivalents of the corresponding alkali metal hydroxide. Additionally, the analogous triethylammonium derivative has been obtained. The resulting compounds have been analyzed as far as possible by elemental analysis, FAB + mass spectrometry, IR, UV-Vis and NMR ( 1 H, 13 C) spectroscopy, and single-crystal X-ray diffraction, showing that the composition of the metal salts can be described by the general formula. The solid-state and solution studies showed that all alkali metal ions participate in the formation of M-O and cation-p(arene) interactions, while M-S interactions are only observed for the larger alkali metals K + , Rb + and Cs + . As expected, within the alkali metal group there is a clear tendency for a decreasing number of M-O bonds in favor of M-S and cation-p(arene) interactions, however, only K + forms a semi-sandwich type complex with h 6 -coordination.

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Structure of lithium 1-pyrrolidinecarbodithioate tetrahydrate, Li.C5H8NS2.4H2O

Cited by 4 publications

References 5 publications

The Structural Characterization of some t‐Butanol Solvates of some Lithium Halides, of LiX : ^tBuOH(1 : 4,6) Ratio

The Structural Characterization of some t‐Butanol Solvates of some Lithium Halides, of LiX : ^tBuOH(1 : 4,6) Ratio

Coordination chemistry of lithium ion: a crystal and molecular structure review

Comparative analysis of M–O, M–S and cation–π(arene) interactions in the alkali metal (Na+, K+, Rb+, Cs+) bis-dithiocarbamate salts of N,N′-dibenzyl-1,2-ethylenediamine

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Structure of lithium 1-pyrrolidinecarbodithioate tetrahydrate, Li.C5H8NS2.4H2O

Cited by 4 publications

References 5 publications

The Structural Characterization of some t‐Butanol Solvates of some Lithium Halides, of LiX : tBuOH(1 : 4,6) Ratio

The Structural Characterization of some t‐Butanol Solvates of some Lithium Halides, of LiX : tBuOH(1 : 4,6) Ratio

Coordination chemistry of lithium ion: a crystal and molecular structure review

Comparative analysis of M–O, M–S and cation–π(arene) interactions in the alkali metal (Na+, K+, Rb+, Cs+) bis-dithiocarbamate salts of N,N′-dibenzyl-1,2-ethylenediamine

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The Structural Characterization of some t‐Butanol Solvates of some Lithium Halides, of LiX : ^tBuOH(1 : 4,6) Ratio

The Structural Characterization of some t‐Butanol Solvates of some Lithium Halides, of LiX : ^tBuOH(1 : 4,6) Ratio