Structure of hexacarbonyl-μ-ethoxymethylidyne-μ-[σ:1–2-η-(1-phenyl-1-propenyl)]-diiron(Fe–Fe), C18H14Fe2O7

Soláns, X.; Font‐Altaba, M.; Ros, Josep; Yáñez, Ramón; Mathieu, René

doi:10.1107/s0108270185007089

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Synthesis Of [Fe2(co)(p-sr)(p-cph=chph)]2

The Complex [ F E 2 ( C O ) ( ~-C I ) ( ~-C H ~H P H ) ]1

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2003

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Cited by 6 publications

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“…In the p-chloro complex (l), the vinylic proton appears at 4.73 p.p.m.' The mass spectra of compounds (5)- (9) show the parent ion M + and the successive loss of six molecules of CO groups, thus confirming the formulation for the thiolato complexes. Furthermore, other observed fragments in all of them are: m/z = 112 (Fe,), 144 (Fe,S), 178 (PhCCPh), 221 (Fe,SPh), and 323 (Fe,CPhCHPhS).…”

Section: The Complex [ F E 2 ( C O ) ( ~-C I ) ( ~-C H ~H P H ) ]supporting

confidence: 55%

“…[R = Et (5), Pr' (ti), cyclo-C,H,, (7), Ph (8), or CH2Ph (9)]. -The corresponding lithium thiolates were prepared by addition of an equimolar amount of a 1.6 mol dm-, solution of butyl-lithium in hexane to a solution of the thiol in the same solvent.…”

Section: Synthesis Of [Fe2(co)(p-sr)(p-cph=chph)]mentioning

confidence: 99%

“…The residual solid was extracted with benzene, filtered and evaporated to dryness. Crystallizations from dichloromethane-metha-no1 gave the complexes (5)- (9) in ca. 50% yield.…”

Section: Synthesis Of [Fe2(co)(p-sr)(p-cph=chph)]mentioning

confidence: 99%

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