Structure of di(n-butyl)bis(N,N-dipropyldithiocarbamato)tin(IV)

Vrábel, Viktor; Lokaj, J.; Kellö, E.; Rattay, V.; Batsanov, A. C.; Struchkov, Yu. T.

doi:10.1107/s010827019101137x

Cited by 6 publications

(3 citation statements)

References 4 publications

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“…Complex 1 was synthesized by a literature method, sodium N , N -diethyldithiocarbamate (3.0 g, 1.3 mmol) and di- n -butyltin dichloride (2.02 g, 0.65 mmol) were dissolved in ethanol (200 mL) and stirred for 30 min, during which time a fine sodium chloride powder precipitated. The reaction mixture was filtered and the ethanol removed from the filtrate by vacuum distillation.…”

Section: Methodsmentioning

confidence: 99%

“…Synthesis of [Sn(C 4 H 9 ) 2 (S 2 CN(C 2 H 5 ) 2 ) 2 ] (1). Complex 1 was synthesized by a literature method, 37 sodium N,N-diethyldithiocarba- (2). Complex 2 was synthesized by dissolving sodium hydroxide (2.3 g, 5.7 mmol), methylbutylamine (5.0 g, 5.7 mmol) in ethanol (100 mL) and stirring for 30 min, followed by the addition of CS 2 (3.47 mL, 5.7 mmol) and stirring for 1 h. A solution of di-n-butyltin dichloride (8.7 g, 2.85 mmol) in ethanol (25 mL) was added dropwise and stirred for 30 min, during which time fine sodium chloride powder precipitated.…”

Section: ■ Experimental Sectionmentioning

confidence: 99%

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Organotin Dithiocarbamates: Single-Source Precursors for Tin Sulfide Thin Films by Aerosol-Assisted Chemical Vapor Deposition (AACVD)

et al. 2013

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A series of diorganotin complexes of dithiocarbamates [Sn(C4H9)2(S2CN(RR′)2)2] (R, R′ = ethyl (1); R = methyl, R′ = butyl (2); R, R′ = butyl (3); R = methyl, R′ = hexyl (4); and [Sn(C6H5)2(S2CN(RR′)2)2] (R, R′ = ethyl (5); R = methyl, R′ = butyl (6); R, R′ = butyl (7); R = methyl, R′ = hexyl (8) were synthesized. Single-crystal X-ray structures of 2, 3, and 8 were determined. Thermogravimetric analysis (TGA) showed single-step decomposition for the complexes 1, 3, and 5–8, and double-step decomposition for the complexes 2 and 4 between 195 °C and 325 °C. Complexes 1–4 were used as single-source precursors for the deposition of SnS thin films by aerosol-assisted chemical vapor deposition (AACVD) at temperatures from 400 °C to 530 °C. Orthorhombic SnS thin films were deposited from all four complexes at all deposition temperatures. The films were characterized by UV–vis spectroscopy, powder X-ray diffraction (p-XRD), Raman spectroscopy, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and also electrical resistivity measurements.

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Section: Methodsmentioning

confidence: 99%

Section: ■ Experimental Sectionmentioning

confidence: 99%

Organotin Dithiocarbamates: Single-Source Precursors for Tin Sulfide Thin Films by Aerosol-Assisted Chemical Vapor Deposition (AACVD)

et al. 2013

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“…The carbon atoms of the alkyl groups bonded to tin show angles C-Sn-C of 136.64 (18)° for complex 2, 129.19 (5)° for 4 and 130.88 (15)° for complex 5, values that are intermediate between cis and trans positions of an octahedral geometry (Lockhart et al, 1985). This distortion may be due to steric effects and the different electronegativities of the ligands bonded to tin (Vrabel et al, 1992), but it has also been ascribed sometimes to crystal packing effects (Tiekink et al, 2000). It is important to note that the n-butyl groups in 4 are disordered.…”

Section: Description Of the Crystal Structuresmentioning

confidence: 94%

Synthesis, spectroscopic characterization and crystal structures of diorganotin (IV) complexes of 2-N-propyl and 2-N-benzyl-amino-1-cyclopentene-1-carbodithioates

López-Cardoso

Rodríguez-Narváez

Vargas-Pineda

et al. 2015

Main Group Metal Chemistry

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Six new diorganotin (IV) complexes, [Ph 2 Sn(Pr-ACDA) 2 ] 1, [Bu 2 Sn(Pr-ACDA) 2 ] 2, [Ph 2 Sn(Bz-ACDA) 2 ] 3, [Bu 2 Sn(Bz-ACDA) 2 ] 4, [Me 2 Sn(Bz-ACDA) 2 ] 5, [t-Bu 2 Sn(Bz-ACDA) 2 ] 6 are reported (where ACDA is the 2-amino-1-cyclopentene-1-carbodithioic anion). The diorganotin complexes were prepared from reactions between sodium N-propyl and N-benzyl-2-amino-1-cyclopentene-1-carbodithioate with R 2 SnCl 2 (R = Ph, Bu, Me, tBu) in a 2:1 ratio. All complexes were characterized by elemental analysis, IR, multinuclear NMR ( 1 H, 13 C, and 119 Sn), FAB + mass spectrometry and in the case of 2, 3 and 5 by single-crystal X-ray diffraction. Both solution and solid state studies show that dithioacid ligands are coordinated to tin in an aniso-bidentate manner. In all complexes coordination takes place only through the carbodithioate moieties. 119 Sn NMR data indicate pentacoordination of tin in solution. The tin coordination geometry, in all three structures is a highly distorted octahedral geometry, where tin is bonded to the four sulfur atoms of the two aniso-bidentate carbodithioate ligands in the equatorial plane and the organic substituents on tin atom in trans-positions. In addition, the crystal structures show the presence of N-H…S hydrogen bonding contacts.

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Synthesis and crystal structures of new complexes of di- and tribenzyltin 2-amino-1-cyclopentene-1-carbodithioates

Tarassoli

Asadi

Hitchcock

2006

Journal of Organometallic Chemistry

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Structure of di(n-butyl)bis(N,N-dipropyldithiocarbamato)tin(IV)

Cited by 6 publications

References 4 publications

Organotin Dithiocarbamates: Single-Source Precursors for Tin Sulfide Thin Films by Aerosol-Assisted Chemical Vapor Deposition (AACVD)

Organotin Dithiocarbamates: Single-Source Precursors for Tin Sulfide Thin Films by Aerosol-Assisted Chemical Vapor Deposition (AACVD)

Synthesis, spectroscopic characterization and crystal structures of diorganotin (IV) complexes of 2-N-propyl and 2-N-benzyl-amino-1-cyclopentene-1-carbodithioates

Synthesis and crystal structures of new complexes of di- and tribenzyltin 2-amino-1-cyclopentene-1-carbodithioates

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