Structure of di(n-butyl)bis(N,N-diethyldithiocarbamato)tin(IV) at 153 K

Tin Organometallic Compounds: Classification and Analysis of Crystallographic and Structural Data: Part 1. Monomeric Derivatives

“…These differ mostly by degree of distortion. Several derivatives contain two crystallographically independent molecules in the same crystal [50,67,75,79,80,82,84,88,93,95,100,110,117,123,124,140,142,168,175,176,187,189,191,197,212,213,218,221,225,245,253,258,270,289,298], In another two derivatives [31,168] three independent molecules are found, and three examples with four such molecules [160,166,204] in rH in rH 00 in CS rH CS CO CO CO CO rH rH CS CO rH CO rH CS <o rH rH -rH CS CS rH CO rH ΙΟ CS …”

Di-n-butylbis[N-(2-methoxyethyl)-N-methyldithiocarbamato-κ2S,S′]tin(IV): crystal structure and Hirshfeld surface analysis

“…Two structures, i.e. R = R 0 = Et (Vrá bel et al, 1992) and R = R 0 = n-Bu (Ramasamy et al, 2013), have two independent molecules in the crystallographic unit and, remarkably, one, i.e. R = i-Pr and R 0 = benzyl (Awang, Baba, Yousof et al, 2010), has Z 0 = 5.…”

Structural Flexibility in Octahedral Tin(IV) Bischelates: Electronic and Hybridization Effects

“…In contrast, the C-Sn-C angle in n Bu 2 Sn[S 2 CN(C 2 H 5 ) 2 ] 2 had been observed to be 140.8(2) o and 132.6(2) o (two molecules). 24 The structural flexibility originates from the flexibility in the hybridization involved in the formation of the three sets of complexes. While the nitrato complexes are formed by using the sp 3 hybrid orbitals, the formation of the dithiocarbamato complexes is best explained on the basis of "sp" hybridization scheme.…”