Structure of bis(diisopropyldithiocarbamato)tellurium(II)

Kumar, Vivek; Aravamudan, G.; Seshasayee, M.; Selvam, Pitchai; Yvon, K.

doi:10.1107/s0108270190002864

Cited by 5 publications

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References 5 publications

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“…Homoleptic dithiocarbamate complexes of both tellurium(II) (215,293,294,296,(302)(303)(304)(305)(306)(307)(308)(309)(310)(311) and tellurium(IV) (293, 294, 296, 302, 304-306, 309, 310, 312-315) are well known. The molecular structures of the bis(dithiocarbamate)tellurium(II) compounds, [Te(S 2 CNR 2 ) 2 ], are analogous to those of the corresponding Se compounds: The Te atom exhibits a planar trapezoidal coordination geometry, with the two dithiocarbamate ligands bound in an anisobidentate fashion [TeÀ ÀS(ave) ¼ 2.52 (short) and 2.83 A ˚(long)].…”

Section: A Homoleptic and Mixed Bidentate Ligand Complexesmentioning

confidence: 99%

Main Group Dithiocarbamate Complexes

Heard¹

2005

Progress in Inorganic Chemistry

194

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Bismuth / 29 1. Homoleptic Complexes / 29 2. Nonhomoleptic Bis(dithiocarbamate) Complexes / 32 3. Mono(dithiocarbamate) Complexes / 36 4. Antimony(V) Complexes / 39 5. Antimony-121 Mo ¨ssbauer Spectroscopy / 39 VI. GROUP 16 (VI A) 40 A. Homoleptic and Mixed Bidentate Ligand Complexes / 40 B. Nonhomoleptic Tellurium(II) Complexes / 44 C. Nonhomoleptic Tellurium(IV) Complexes / 47 1. Tris(dithiocarbamate) Complexes / 47 2. Bis(dithiocarbamate) Complexes / 49 3. Mono(dithiocarbamate) Complexes / 51 4. Tellurium-125 NMR and Mo ¨ssbauer Spectroscopy / 53

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