The enthalpies of solution of BaCmO3 and BaCfO3 in 1.00 mol dm -3 HCIO4 were measured at 298.15 +0.05 K and p°= 101.325 kPa as -(345.3 +4.7) and -(347.2+ 1.9) kJ mo1-1, respectively. The resulting standard molar enthalpies of formation, AfH°(BaCmO3, cr) = -(1517.8 + 7.1) kJ mol-1 and AfH°(BaCfO3, cr) = -(1477.9 + 5.6) kJ mo1-1, together with other corresponding experimental values for several lanthanide, actinide and transition metal complex oxides with barium and strontium, are used to estimate the molar enthalpies of formation of a number of homologous actinide compounds. The present results also provide additional information on the standard molar enthalpy of formation of CfO2 and on the Cf4+/Cf 3÷ standard potential.