Abstract:Polynuclear metal clusters frequently feature geometric structural features not common in traditional coordination chemistry. These structures are of particular interest to bioinorganic chemists studying metallocluster enzymes, which frequently possess remarkably unusual inorganic structures. The structure of the manganese cluster μ-oxido-di-μ-phenoxido-hexa-μ-phenoxido-hexakis(pyridine-κN)hexamanganese(II) pyridine monosolvate, [Mn(CHO)O(CHN)]·CHN or Mn(μ-OPh)(μ-OPh)(μ-O)(Py)·Py, containing an unusual trigona… Show more
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