Abstract:Results from X-ray diffraction determination have shown that (IS,2E,4R,6R, 7E.l1.5, and (IS,2E,4s,6R,7E,7,6, exist as ~onformT3s A and B about the 5,6-bond. An analysis of the Hand C NMR spectra suggests that these conformations are retained in solution and that other cembranold alcohols or acetates are conformationally reminiscent of either 1 or 2. \He have now carried out molecular mechanics (MM2) calculations using X-ray data of 1 and 2 as Inputs. These show that for each compound, the geometry at the local… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.