Structure of 2-benzimidazolesulfonic acid monohydrate

Chidambaram, S.; Aravamudan, G.; Seshasayee, M.

doi:10.1107/s010827018800071x

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“…For examples of Ni-sulfonate complexes and MOFs, see: Lobana et al (2004); Forbes & Sevov (2009); Kim et al (2004); Yang et al (2010). A small number of structurally characterized imidazole sulfonates are known, see: Kuhn et al (2001Kuhn et al ( , 2002; Chidambaram et al (1988). The 2-ethyl-4-methyl-5sulfonate ligand is described by Purdy et al (2007) and Purdy & Butcher (2011).…”

Section: Related Literaturementioning

confidence: 99%

Diaquabis(2-ethyl-5-methylimidazole-4-sulfonato-κ² N ³,O)nickel(II) dihydrate

Purdy¹,

Butcher²

2013

Acta Cryst E

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In the title complex, [Ni(C6H9N2O3S)2(H2O)2]·2H2O, the NiII atom lies on an inversion center and is chelated by N and O atoms of two symmetry-equivalent imidazolesulfonate ligands in the basal plane, and two water O atoms in axial positions in an overall octahedral configuration. The crystal structure displays O—H⋯O and N—H⋯O hydrogen bonds, which connect the components into an extended three-dimensional network.

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