“…The exceptional characteristics of rare gas atoms, combined with the growing interest in studying alkali atoms following the observation of the photo-association of cold alkali atoms and their Bose–Einstein condensation [ 4 ], have made the interaction between alkali atoms and rare gas atoms a prominent research theme in numerous studies. Notably, both experimental and theoretical works [ 4 , 11 , 12 , 13 , 14 , 15 , 16 , 17 , 18 , 19 , 20 , 21 , 22 , 23 , 24 , 25 , 26 , 27 , 28 , 29 ] have been dedicated to exploring the interaction between alkali neutral/ionic dimers and rare gas atoms. The primary focus of these studies is calculating the potential energy surfaces (PES) of dimers with a single rare gas atom.…”