Eggshell, a naturally occurring source of nanostructured
CaCO3, has the potential to serve as a sacrificial template
for
mesoporous carbon. In this direction, eggshell-templated lignin carbon(s)
was prepared for the removal of dyes. The prepared material(s) exhibited
a high Brunauer–Emmett–Teller (BET) surface area, i.e.,
LES 1:2; 886 m2/g and LES 1:1; 315 m2/g. LES
1:2 exhibited comparatively higher methyl orange adsorption capacity
in a batch system viz, the maximum MO adsorption
capacity of LES 1:2 was 262 mg/g. Kinetic and thermodynamic studies
were used to investigate the intuition of dye adsorption. The experimental
data best fitted with the pseudo-second-order model, and thermodynamic
studies revealed the dye adsorption to be spontaneous. Furthermore,
LES 1:2 demonstrated remarkable MO removal efficiency, ≥99%
in the cocontaminated/simulated effluent. The characteristics of the
fabricated materials were further analyzed through Raman spectroscopy,
Brunauer–Emmett–Teller (BET) analysis, field emission
scanning electron microscopy (FESEM), and X-ray photoelectron spectroscopy
(XPS).