Abstract:Besides numerous known iridals, which are unusual monoNaBH 4 . The products 15a,b and 16a,b of this reaction sequence were isolated and their structures elucidated by or bicyclic triterpenoids of Iridaceae, lipid extracts of Tigridia pavonia bulbs contain tigridial (17), a new spirobicyclic spectroscopic techniques. From these results structure 17 was inferred for the new natural product, which was confirmed hemiacetal with a conjugated pentaene moiety in the terpenoid side chain. The isolated natural product … Show more
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