Structure and thermal decomposition of μ-1,1-azido bridged dinuclear Fe(III) complexes

Abstract

Dinuclear Fe(III) complex / X-ray diffraction / Single crystal structure analysis / Magnetic properties / Thermal analysis Abstract. Fe(III) complexes were prepared by the reaction of two different ONNO type Schiff bases N,N 0 -bis (salicylidene)-1,3-propanediamine (LH 2 ) and N,N 0 -bis (salicylidene)-2,2 0 -dimethyl-1,3-propane diamine (LDMH 2 ) in N À 3 containing medium. The X-ray diffraction studies revealed that the complexes are of dinuclear type connected with m-1,1-azido bridges. It was observed from the