Structure and Properties of the Condensation Product of 2-Oxo-1,2-dihydroquinoline-3-carbaldehyde with Stearic Acid Hydrazide and Its Complexes with Cu(II) and Ni(II)
“…The IR spectrum of the ligand system contains intense CQN absorption bands from the pyridine ring at 1468-1485 cm À1 and CQN from azomethine fragments at 1695-1703 cm À1 depending on substitutes R. These frequencies are well matched with the experimental values. 39,40 In the Ru(II) complexes, CQN het undergoes a low-frequency shift by 20-90 cm À1 with increasing intensity. The azomethine bonds CQN have the same trend with more significant shifts by 100-120 cm À1 .…”
New complexes of ruthenium and iron based on the bis-azomethine condensation product of 2,6-diformyl-4R-pyridine and para-aminocinnamic acid have been theoretically studied. A widely studied ruthenium-based black dye sensitizer (N719) based...
“…The IR spectrum of the ligand system contains intense CQN absorption bands from the pyridine ring at 1468-1485 cm À1 and CQN from azomethine fragments at 1695-1703 cm À1 depending on substitutes R. These frequencies are well matched with the experimental values. 39,40 In the Ru(II) complexes, CQN het undergoes a low-frequency shift by 20-90 cm À1 with increasing intensity. The azomethine bonds CQN have the same trend with more significant shifts by 100-120 cm À1 .…”
New complexes of ruthenium and iron based on the bis-azomethine condensation product of 2,6-diformyl-4R-pyridine and para-aminocinnamic acid have been theoretically studied. A widely studied ruthenium-based black dye sensitizer (N719) based...
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