Structure and Properties of Copper(II) and Cobalt(II) Halide Complexes with N–Heterocycles of Composition (HL)n[MHal4]

Protsenko, Alexandra N.; Garifova, Veronika V.; Shakirova, O. G.

doi:10.1007/978-3-030-69421-0_28

Cited by 1 publication

(1 citation statement)

References 13 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…A copper(II) chloride complex with organic heterocyclic nitrogen-containing cations with the composition (2,3,5-TPhTz) 2 [CuCl 4 ] (where 2,3,5-TPhTz is 2,3,5-triphenyltetrazolium) was used as a catalyst. It had been obtained previously [ 44 ] ( Figure 1 ).…”

Section: Methodssupporting

confidence: 67%

Recycling of Epoxy/Fiberglass Composite Using Supercritical Ethanol with (2,3,5-Triphenyltetrazolium)2[CuCl4] Complex

Protsenko¹,

Protsenko²,

Shakirova³

et al. 2023

Polymers

Self Cite

View full text Add to dashboard Cite

The widespread use of polymer composite materials (PCM) leads to an increase in non-recyclable waste. This paper discusses the feasibility of recycling fiberglass with an epoxy matrix by solvolysis in ethanol under supercritical conditions. The solvolysis process completes successfully within four hours in an environment of a pure solvent containing 10% water at a temperature of 280 °C when the solvent passes into the supercritical state. The treatment time increases up to 10 h at a process temperature of 250 °C. When using a coordination compound of copper(II) chloride with organic chloride salt having 2,3,5-triphenyltetrazolium as the counterion, having the composition of (2,3,5-triphenyltetrazolium)2[CuCl4], the treatment time is reduced. The addition of the complex of 5% by weight makes it possible to completely remove the epoxy matrix at a temperature of 250 °C for two hours. The products separated from the solvolysis liquid were studied by infrared spectroscopy. The resulting fibers were examined by thermogravimetric analysis and scanning electron microscopy. The residual strength of the recovered fibers is 98%. Thus, the resulting fibers can be reused in the composite industry. Including both for the production of decorative products and for the production of structural products made of polymer composite materials.

show abstract

Section: Methodssupporting

confidence: 67%