Structure and magnetism of novel mixed-anionic-group compounds M2(SeO3)(Te3O7) (M = Co2+, Ni2+)

Zhang, Wanwan; He, Zhangzhen; Qiu, Chaoqun; Cui, Meiyan; Zhao, Zhiying; Chen, Sihuai

doi:10.1016/j.jallcom.2017.09.008

Cited by 2 publications

(2 citation statements)

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“…However, these experimental systems are independent of different crystal structures. Isostructural 1D spin chain systems with different spin S have less been systematically investigated and discussed, despite there being several reports. − It is crucial to experimentally synthesize isostructural chain compounds with various spin values S for systematically investigating the quantum magnetism of 1D spin chain systems.…”

Section: Introductionmentioning

confidence: 99%

Analogous Chain Selenite Chlorides Ba₂M(SeO₃)₂Cl₂ (M = Cu²⁺, Ni²⁺, Co²⁺, Mn²⁺) and Pb₂Cu(SeO₃)₂Cl₂ with Tunable Spin S: Syntheses and Characterizations

Yalikun,

Wang,

et al. 2024

Inorg. Chem.

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A series of analogous chain selenite chlorides Ba 2 M(SeO 3 ) 2 Cl 2 (M = Cu 1, Ni 2, Co 3, Mn 4) and Pb 2 Cu(SeO 3 ) 2 Cl 2 5 with tunable spin S from S = 1/2 to S = 5/2 have been hydrothermally synthesized and characterized. These analogues crystallized in the orthorhombic Pnnm space group (monoclinic P2 1 /n space group for 5) all containing M 2+ −SeO 3 −M 2+ spin chains, which are further separated by the Ba 2+ ions (Pb 2+ for 5). The magnetic susceptibility results of 1, 2, and 5 show broad maxima around 80.0, 18.9, and 78.0 K, respectively, indicating good one-dimensional (1D) magnetism. Meanwhile, no long-range order (LRO) is observed down to 2 K for both 1 and 5, while the isostructural compounds 2, 3, and 4 exhibit LRO at 3.4 K, 10.8 K, and 5.7 K, respectively, which are further confirmed by the heat capacity and electron spin resonance results, as well as the observed spin-flop transitions in the M−H curves measured at 2 K below T N . The magnetizations of 1−5 at 7 T are still far from saturation. In addition, thermal stability and FT-IR and UV−vis−NIR spectroscopy of 1−5 are reported.

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Section: Introductionmentioning

confidence: 99%

Analogous Chain Selenite Chlorides Ba₂M(SeO₃)₂Cl₂ (M = Cu²⁺, Ni²⁺, Co²⁺, Mn²⁺) and Pb₂Cu(SeO₃)₂Cl₂ with Tunable Spin S: Syntheses and Characterizations

Yalikun,

Wang,

et al. 2024

Inorg. Chem.

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“…In addition, a spin-glass-like dynamic relaxation is observed in the cobalt-based hydroxysulfate, i.e, Na2Co3(OH)2(SO4)3(H2O)4 [15] exhibiting ferrimagnetic chains, while the authors Vilminot et al [16], reported a large coercivity of 70 kOe at 1.8 K in the ferrimagnet, K2Co3(OH)2(SO4)3(H2O)2. Moreover, several inorganic compounds and cobalt-organic frameworks with spin-cluster and/or spin-chain structures have been studied [17][18][19][20][21][22][23]. For instance, Cobalt-based compounds showing one-dimensional spinchain structure such as Co3(BPO4)2(PO4)(OH)3 [19]and CoCl2.2H2O [24] were reported with a step-like magnetization curves.…”

Section: Introductionmentioning

confidence: 99%

Unconventional spin-glass-like state in AgCo2V3O10, the novel magnetically frustrated material

Hadouchi

Assani

Saadi

et al. 2019

Journal of Magnetism and Magnetic Materials

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Single crystals of a new silver and-cobalt based vanadate AgCo2V3O10 were grown from a melted mixture. The crystal structure determination reveals that this new vanadate crystallizes in triclinic system with space group P1 ̅ . The structure of the titled compound is constructed from CoO6 octahedra and VO4 tetrahedra sharing edges and vertices leading to an open threedimensional framework delimiting tunnels along [001], where the Ag cations are located. The bands observed in Raman spectrum were assigned to corresponding vibrations of the VO4 groups. DC and AC magnetization (susceptibility) measurements revealed the spin-glass (SG) -type transition below a frequency-independent temperature Tf(H) that is nearly independent on the applied magnetic field. Magnetic field H> 10 kOe induces the spin glass-antiferromagnet.These observations brings AgCo2V3O10 into the class of geometrically frustrated magnetic systems.

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Structure and magnetism of novel mixed-anionic-group compounds M2(SeO3)(Te3O7) (M = Co2+, Ni2+)

Cited by 2 publications

References 35 publications

Analogous Chain Selenite Chlorides Ba₂M(SeO₃)₂Cl₂ (M = Cu²⁺, Ni²⁺, Co²⁺, Mn²⁺) and Pb₂Cu(SeO₃)₂Cl₂ with Tunable Spin S: Syntheses and Characterizations

Analogous Chain Selenite Chlorides Ba₂M(SeO₃)₂Cl₂ (M = Cu²⁺, Ni²⁺, Co²⁺, Mn²⁺) and Pb₂Cu(SeO₃)₂Cl₂ with Tunable Spin S: Syntheses and Characterizations

Unconventional spin-glass-like state in AgCo2V3O10, the novel magnetically frustrated material

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Structure and magnetism of novel mixed-anionic-group compounds M2(SeO3)(Te3O7) (M = Co2+, Ni2+)

Cited by 2 publications

References 35 publications

Analogous Chain Selenite Chlorides Ba2M(SeO3)2Cl2 (M = Cu2+, Ni2+, Co2+, Mn2+) and Pb2Cu(SeO3)2Cl2 with Tunable Spin S: Syntheses and Characterizations

Analogous Chain Selenite Chlorides Ba2M(SeO3)2Cl2 (M = Cu2+, Ni2+, Co2+, Mn2+) and Pb2Cu(SeO3)2Cl2 with Tunable Spin S: Syntheses and Characterizations

Unconventional spin-glass-like state in AgCo2V3O10, the novel magnetically frustrated material

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Analogous Chain Selenite Chlorides Ba₂M(SeO₃)₂Cl₂ (M = Cu²⁺, Ni²⁺, Co²⁺, Mn²⁺) and Pb₂Cu(SeO₃)₂Cl₂ with Tunable Spin S: Syntheses and Characterizations

Analogous Chain Selenite Chlorides Ba₂M(SeO₃)₂Cl₂ (M = Cu²⁺, Ni²⁺, Co²⁺, Mn²⁺) and Pb₂Cu(SeO₃)₂Cl₂ with Tunable Spin S: Syntheses and Characterizations