Structure and magnetism of coordination polymers containing dicyanamide and tricyanomethanide

Self-assembly of iron TCPP (meso-tetra(4-carboxyphenyl)porphyrin) into a chiral 2D coordination polymer

“…The result is a uninodal 4-c net (sql/Shubnikov tetragonal plane net {4 4 ;6 2 }). Several examples of compounds exhibiting the same topology can be found in literature [41][42][43][44][45][46]. The fact that such a complicated structure extends in that simple fashion is remarkable, as well as the fact that for [FeTCPP] the extension of the structure takes place through two of the four equatorial positions and both axial ones.…”

1D Chain Crystal Structure of Copper(II) Oxalate Containing a 4,4'-Bipyridine and 1,10-Phenanthroline Ligands: [Cu2(ox)(4,4'-bpy)(phen)2](NO3)2

“…[4][5][6] The most commonly used strategy for designing such materials relies on the utilization of multidentate N-or O-donor ligands which have the capacity to bridge between metal centers to form polymeric structures. For example, 4,4'-bipyridine (4,4'-bpy) is an excellent ligand and a number of one-, twoand three-dimensional infinite metal-4,4'-bpy frameworks have been generated.…”

Wireless radio frequency detection of greatly simplified polymeric membranes based on a multifunctional ionic liquid

“…Dicyanamide (DCA) -has previously been termed a pseudohalide with rather complex binding stoichiometry [37]. Complexation of this ligand with heavy metals results in net neutral complexes of 1, 2 and 3 dimensions [38,39] plus electrochemically neutral co-ordinated polymers [40].…”