Structure and magnetic studies of geometrically frustrated disordered pyrochlores A$_{2}$Zr$_{2}$O$_{7}$: (A = Eu, Gd, Er)

Abstract

The spin ice system Dy2Ti2O7 exhibits strong frequency-dependent spin-freezing at ∼ 16 K temperature. Although it has been a matter of discussion for years, the origin of this unusual spin freezing is still unknown. The replacement of Ti with isovalent Zr leads to the dynamic magnetic ground state at low temperatures in Dy2Zr2O7 and prevents the formation of high-temperature spin freezing. Interestingly the high-temperature spin freezing re-emerges in the presence of the magnetic field. In this direction, we have studied a series of disordered pyrochlore oxides A2Zr2O7 (A = Eu, Gd, Er) and compared their crystal structure, magnetic, and heat capacity behavior with that of Dy2Zr2O7 and Ho2Zr2O7 systems. Our study shows that depending on the disordered parameter, the spin-freezing behavior can be retained by slowing down the spin dynamic with a suitable choice of the magnetic field. We observe that unlike titanates, modification at the rare earth site does not make considerable change in the magnetic ground state of these zirconates compounds.