“…In the (Mn,Fe) 2 (P,Si) family of compounds, Mn atoms show a preference to the pyramidal 3g site, which is marked by a larger magnetic moment, whereas Fe atoms preferentially occupy 3f sites, associated with a smaller magnetic moment [7,31]. In the Fe-rich region, the 3f site is fully occupied by Fe, and the 3g site is partially occupied by Mn and partially by Fe [32]. A schematic representation of the crystal structure is shown in Fig.…”