Structure and isotope effects upon the thermal decomposition of carbamates of highly congested tertiary alcohols

Lomas, John S.; Thorne, Melanie P.

doi:10.1039/p29820000221

Cited by 10 publications

(7 citation statements)

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“…13 C-12 C (µ=6.24), 2 H-12 C (µ=1.71), 16 Table 3). The heavier isotopic molecules have lower diffusion velocity, mobility, evaporation rate, thermal decomposition and rate of reaction, but higher binding energy than the lighter molecules [54][55][56][57]. The biofield energy treated nerolin has the higher isotopic abundance ratio.…”

Section: Resultsmentioning

confidence: 99%

Gas Chromatography-Mass Spectrometry Based Isotopic Abundance Ratio Analysis of Biofield Energy Treated Methyl-2-napthylether (Nerolin)

Trivedi¹,

Branton²,

Trivedi³

et al. 2016

AJPC

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Methyl-2-napthylether (nerolin) is an organic compound and has the applications in pharmaceutical, and perfume industry. The stable isotope ratio analysis is increasing importance in various field of scientific research. The objective of the current study was to evaluate the effect of the biofield energy treatment on the isotopic abundance ratios of P M+1 /P M (2 H/ 1 H or 13 C/ 12 C or 17 O/ 16 O) and P M+2 /P M (18 O/ 16 O) in nerolin using the gas chromatography-mass spectrometry (GC-MS). The compound nerolin was divided into two parts-one part was control sample (untreated), and another part was considered as biofield energy treated sample which was received the biofield energy treatment through the unique biofield energy transmission process by Mr. Mahendra Kumar Trivedi (also known as The Trivedi Effect ®). The biofield energy treated nerolin was analyzed at different time intervals and were represented as T1, T2, T3, and T4 in order to understand the effect of the biofield energy treatment on isotopic abundance ratio with respect to the time. From the GC-MS spectral analysis, the presence of the molecular ion peak C 11 H 10 O + (m/z 158) along with major fragmented peaks C 10 H 7 O-(m/z 143), C 10 H 8 (m/z 128), C 9 H 7 + (m/z 115), C 7 H 5 + (m/z 89), C 5 H 3 + (m/z 63), C 4 H 3 + (m/z 51), and C 3 H 3 + (m/z 39) were observed in both control and biofield treated samples. Only, the relative peak intensities of the fragmented ions in the biofield treated nerolin was notably changed as compared to the control sample with respect to the time. The isotopic abundance ratio analysis of nerolin using GC-MS revealed that the isotopic abundance ratio of P M+1 /P M in the biofield energy treated nerolin at T1, T2, T3, and T4 was increased by 0.17, 135.83, 9.13, and 25.57%, respectively as compared to the control sample. Likewise, the isotopic abundance ratio of P M+2 /P M at T1, T2, T3, and T4 was increased by 2.38, 138.10, 13.10, and 32.14%, respectively in the biofield treated nerolin as compared to the control sample. Overall, the isotopic abundance ratios of P M+1 /P M (2 H/ 1 H or 13 C/ 12 C or 17 O/ 16 O) and P M+2 /P M (18 O/ 16 O) were significantly increased in the biofield energy treated sample as compared to the control sample with respect to the time. It is concluded that Mr. Trivedi's biofield energy treatment has the significant impact on alteration in isotopic abundance of nerolin as compared to the control sample. The biofield treated nerolin might display different altered physicochemical properties and rate of reaction and could be an important intermediate for the production of pharmaceuticals, chemicals, and perfumes in the industry.

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Section: Resultsmentioning

confidence: 99%

Gas Chromatography-Mass Spectrometry Based Isotopic Abundance Ratio Analysis of Biofield Energy Treated Methyl-2-napthylether (Nerolin)

Trivedi¹,

Branton²,

Trivedi³

et al. 2016

AJPC

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“…The results showed that reduced mass were increased in the case of heavier isotopes as compared to normal bond ( Table 4). As per the literature, the heavier isotopic molecules have lower diffusion velocity, mobility, evaporation rate, thermal decomposition and reaction rate, but having higher binding energy than lighter molecules [56][57][58][59]. The biofield energy treated o-and m-nitrophenol have the higher isotopic abundance ratios.…”

Section: Figure 5 Percent Change In the Isotopic Abundance Ratio Of mentioning

confidence: 87%

Evaluation of Isotopic Abundance Ratio in Biofield Energy Treated Nitrophenol Derivatives Using Gas Chromatography-Mass Spectrometry

Trivedi¹

2016

AJCHE

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Nitrophenols are the synthetic organic chemicals used for the preparation of synthetic intermediates, organophosphorus pesticides, and pharmaceuticals. The objective of the present study was to evaluate the effect of biofield energy treatment on the isotopic abundance ratios of P M+1 /P M , and P M+2 /P M in o-and m-nitrophenol using the gas chromatography-mass spectrometry. The o-and m-nitrophenol were divided into two parts -one part was control sample, and another part was considered as biofield energy treated sample, which received Mr. Trivedi's biofield energy treatment (The Trivedi Effect ® ). The biofield energy treated nitrophenols having analyzed at different time intervals were designated as T1, T2, T3, and T4. The GC-MS analysis of both the control and biofield treated samples indicated the presence of the parent molecular ion peak of o-and mnitrophenol (C 6 H 5 NO 3 + ) at m/z 139 along with major fragmentation peaks at m/z 122, 109, 93, 81, 65, and 39. The relative peak intensities of the fragmented ions in the biofield treated o-and m-nitrophenol were notably changed as compared to the control sample with respect to the time. The isotopic abundance ratio analysis using GC-MS revealed that the isotopic abundance ratio of P M+1 /P M in the biofield energy treated o-nitrophenol at T2 and T3 was significantly increased by 14.48 and 86.49%, respectively as compared to the control sample. Consequently, the isotopic abundance ratio of P M+2 /P M in the biofield energy treated sample at T2 and T3 was increased by 11.36, and 82.95%, respectively as compared to the control sample. Similarly, in m-nitrophenol, the isotopic abundance ratio of P M+1 /P M in the biofield energy treated sample at T1, T3, and T4 was increased by 5.82, 5.09, and 6.40%, respectively as compared to the control sample. Subsequently, the isotopic abundance ratio of P M+2 /P M at T1, T2, T3 and T4 in the biofield energy treated m-nitrophenol was increased by 6.33, 3.80, 16.46, and 16.46%, respectively as compared to the control sample. Overall, the isotopic abundance ratios of P M+1 /P M (

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“…As per the literature, the heavier isotopic molecules have lower diffusion velocity, mobility, evaporation rate, thermal decomposition and reaction rate, but having higher binding energy than lighter molecules [45][46][47][48]. The biofield energy treated p-DCB have the higher isotopic abundance ratios.…”

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confidence: 87%

Determination of Isotopic Abundance Ratio of Biofield Energy Treated 1,4-Dichlorobenzene Using Gas Chromatography-Mass Spectrometry (GC-MS)

Trivedi¹

2016

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Abstract:The objective of the current study was to evaluate the effect of biofield energy treatment on the isotopic abundance ratios of P M+1 /P M , P M+2 /P M , P M+3 /P M and P M+4 /P M in p-DCB using gas chromatography-mass spectrometry (GC-MS). The p-DCB was divided into two parts -one part was control sample, and another part was considered as the treated sample which was subjected to biofield energy treatment (The Trivedi Effect ® ). T1, T2, T3, and T4 were referred the biofield treated p-DCB having analyzed at different time intervals. The GC-MS analysis of both the control and biofield treated p-DCB indicated the presence of the parent molecular ion peak at m/z 146 along with four major fragmentation peaks at m/z 111, 75, 55 and 50. The relative peak intensities of the fragmented ions in the biofield treated p-DCB were notably changed as compared to the control sample with respect to the time. The isotopic abundance ratio analysis using GC-MS revealed that the isotopic abundance ratio of P M+1 /P M at T1, T2, T3, and T4 (biofield energy treated p-DCB) was significantly increased by 10.87, 83.90, 225.16, and 241.15%, respectively as compared to the control sample. Consequently, the percentage change in the isotopic abundance ratio of P M+2 /P M at T1, T2, and T3 (biofield energy treated p-DCB) was enhanced by 4.55, 9.49, and 1.80%, respectively as compared to the control sample. Beside these, another two isotopic molecular ion peaks at m/z 149 and 150 were found in the GS-MS spectra due to arise from the contributions of various combinations of 2 H, 13 C, and 37Cl. The isotopic abundance ratios of P M+3 /P M in biofield energy treated sample at T1, T2, T3, and T4 was significantly increased by 15.14, 82.57, 192.43, and 218.31%, respectively as compared to the control sample. Similarly, the P M+4 /P M in biofield energy treated sample at T1, T2, T3, and T4 was significantly increased by 13.80, 86.66, 186.13, and 204.29%, respectively as compared to the control sample. Overall, the isotopic abundance ratios of P M+1 /P M ( Cl/ 35 Cl) were significantly enhanced in the biofield energy treated p-DCB. The biofield treated p-DCB has shown improved isotopic abundance ratios that might have altered the physicochemical properties, thermal properties and rate of reaction. Biofield treated p-DCB might be useful in pharmaceutical and chemical industries as intermediates during the manufacturing of pharmaceuticals and chemicals by monitoring the rate of chemical reaction.

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Structure and isotope effects upon the thermal decomposition of carbamates of highly congested tertiary alcohols

Cited by 10 publications

References 0 publications

Gas Chromatography-Mass Spectrometry Based Isotopic Abundance Ratio Analysis of Biofield Energy Treated Methyl-2-napthylether (Nerolin)

Gas Chromatography-Mass Spectrometry Based Isotopic Abundance Ratio Analysis of Biofield Energy Treated Methyl-2-napthylether (Nerolin)

Evaluation of Isotopic Abundance Ratio in Biofield Energy Treated Nitrophenol Derivatives Using Gas Chromatography-Mass Spectrometry

Determination of Isotopic Abundance Ratio of Biofield Energy Treated 1,4-Dichlorobenzene Using Gas Chromatography-Mass Spectrometry (GC-MS)

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