Structure and dynamics of biodegradable polyurethane-silk fibroin composite materials in the dry and hydrated states studied using 13C solid-state NMR spectroscopy

Asakura, Tetsuo; Ibe, Yusuke; Jono, Takaki; Naito, Akira

doi:10.1016/j.polymdegradstab.2021.109645

Cited by 8 publications

(1 citation statement)

References 73 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Although broad peaks are usually found for amorphous materials, − the spectra of the feedstock can be interpreted as compatible with methylene diphenyl diisocyanate linked by 2-methylpropane-(1,3)-diol.…”

Section: Resultsmentioning

confidence: 99%

Subcritical Hydrothermal Liquefaction as a Pretreatment for Enzymatic Degradation of Polyurethane

et al. 2022

View full text Add to dashboard Cite

Enzymatic digestion is a promising alternative in the upconversion of plastic waste compared to traditional chemical recycling methods, because it warrants the use of milder conditions. However, enzymes are hardly able to penetrate the bulk of the plastic material; thus, a pretreatment is necessary to promote the reaction. In this study we investigate hydrothermal liquefaction as a thermal pretreatment of a commercial polyurethane before performing an enzymatic digestion. The feedstock is a rigid polyurethane foam. The structure and chemical composition of the feedstock were analyzed through FTIR analysis and solid-state 13 C NMR. The polyurethane was then subjected to hydrothermal liquefaction using either ultrapure water or KOH as a basic catalyst. Enzymatic digestion was then performed on the organic fraction obtained from both experiments using a lipase extracted from Candida rugosa. The LC-MS analysis of the digests shows an increase in some signal intensities due to the degradation of oligomeric fragments. This new way of recycling allows the recovery of important chemicals such as quinolines and 4,4′-methylenedianiline. With this study we demonstrate that hydrothermal liquefaction coupled with enzymatic digestion is a suitable alternative for handling polyurethane waste.

show abstract

Section: Resultsmentioning

confidence: 99%